In:
The Journal of Chemical Physics, AIP Publishing, Vol. 33, No. 2 ( 1960-08-01), p. 598-600
Abstract:
The microwave spectra of several isotopic species of formyl fluoride have been investigated in the region 11–46 kMc. Both parallel and perpendicular transitions have been assigned. The effective rotational constants for HC12OF are (Mc) a=91153.6, b=11760.0, c=10396.8; for HC13OF, a=88475.3, b=11755.2, c=10357.3; for DC12OF, a=65090.1, b=11761.7, c=9941.7. From these constants the structural parameters are calculated to be rCF=1.341 A, rCO=1.183 A, rCH=1.100 A, ≰ FCO=122.7°, ≰ HCF≈108°, ≰ HCO≈129°. Measurements of the Stark effect lead to a value of 2.02±0.02 debyes for the dipole moment.
Type of Medium:
Online Resource
ISSN:
0021-9606
,
1089-7690
Language:
English
Publisher:
AIP Publishing
Publication Date:
1960
detail.hit.zdb_id:
3113-6
detail.hit.zdb_id:
1473050-9
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