In:
Journal of Applied Physics, AIP Publishing, Vol. 99, No. 8 ( 2006-04-15)
Abstract:
We report a study of magnetic properties of a series of hexanuclear manganese metallamacrocycles {Mn6}. The magnetic properties are characterized by antiferromagnetic (AFM) coupling constants J1∕kB≈−4.0K, between the nearest neighbors, and J2∕kB≈−1.2K, between the next-nearest neighbors. The temperature dependence of H1 NMR linewidth is observed to be consistent with the AFM singlet ground state with a total spin ST=0. H1 nuclear spin-lattice relaxation rate 1∕T1 shows a strong enhancement at low temperatures with a peak around T≈J1, as commonly observed in AFM molecular rings and clusters.
Type of Medium:
Online Resource
ISSN:
0021-8979
,
1089-7550
Language:
English
Publisher:
AIP Publishing
Publication Date:
2006
detail.hit.zdb_id:
220641-9
detail.hit.zdb_id:
3112-4
detail.hit.zdb_id:
1476463-5
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