In:
Applied Physics Letters, AIP Publishing, Vol. 82, No. 23 ( 2003-06-09), p. 4134-4136
Abstract:
A large frequency dependence of the maximum dielectric constant temperature was observed for LiTaO3 nanocrystals (the diameter ≈20 Å) dispersed in mesoporous silicate. At the applied field frequency of 100 kHz, the maximum temperatures in the real and imaginary parts were 365 and 345 °C, respectively. The maximum temperature in the real part is apparently lower than the paraelectric–ferroelectric transition temperature (645 °C) of bulk LiTaO3. The maximum temperature in the imaginary part rose from 285 to 420 °C with increasing frequency from 10 to 1000 kHz. Since the bulk LiTaO3 shows no relaxor behavior, such superparaelectric behavior is obviously a consequence of nanominiaturization of LiTaO3 crystal and insignificant cooperative interactions between the nanoparticles.
Type of Medium:
Online Resource
ISSN:
0003-6951
,
1077-3118
Language:
English
Publisher:
AIP Publishing
Publication Date:
2003
detail.hit.zdb_id:
211245-0
detail.hit.zdb_id:
1469436-0
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