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  • AIP Publishing  (93)
  • 1
    In: The Journal of Chemical Physics, AIP Publishing, Vol. 152, No. 20 ( 2020-05-29)
    Abstract: Alloys are active in CO2 electroreduction due to their unique electronic and geometric structures. Nevertheless, CO2 reduction selectivity is still low due to the low concentration of CO2 near the catalyst surface and the high energy barrier for CO2 activation. This paper describes an AuCu nanochain aerogel (NC–AuCu) with abundant grain boundaries (GBs) that promote the accumulation and activation of CO2 for further electrochemical reduction, employing in situ attenuated total reflection surface-enhanced infrared absorption spectroscopy and density functional theory calculations. GBs can induce a strong local electric field to concentrate the electrolyte cations and thus accumulate CO2 near the catalyst surface. NC–AuCu exhibits a superior Faradaic efficiency of close to 100% for CO2 electroreduction to CO at an extremely low overpotential of 110 mV with a high CO partial current density of 28.6 mA cm−2 in a flow cell. Coupling with a Si solar cell to convert solar energy to CO, a very high conversion efficiency of ∼13.0% is achieved. It potentially provides broad interest for further academic research and industry applications.
    Type of Medium: Online Resource
    ISSN: 0021-9606 , 1089-7690
    Language: English
    Publisher: AIP Publishing
    Publication Date: 2020
    detail.hit.zdb_id: 3113-6
    detail.hit.zdb_id: 1473050-9
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  • 2
    Online Resource
    Online Resource
    AIP Publishing ; 2009
    In:  Journal of Applied Physics Vol. 105, No. 9 ( 2009-05-01)
    In: Journal of Applied Physics, AIP Publishing, Vol. 105, No. 9 ( 2009-05-01)
    Abstract: Sn 1 − x Co x O 2 films have been fabricated to study the local structure of Co dopant and the mediation effects of donor defects (oxygen vacancies and Sn interstitials) on magnetic properties. Compared to as-grown film, the ferromagnetism is evidently enhanced after annealing in vacuum at 400 °C due to the increase in oxygen vacancies. While annealing at higher temperature, the ferromagnetism declines because of the domination of decrease in Sn interstitials over increase in oxygen vacancies in the films. The incorporation of Co dopant as well as the presence of oxygen vacancies and Sn interstitials is verified using x-ray absorption fine structure spectroscopy. The variations in the concentration of defects as a function of annealing temperature are obtained by positron annihilation spectroscopy technique. Additionally, the changes in structure and ferromagnetism after annealing in different atmospheres further demonstrate the crucial roles of oxygen vacancies and Sn interstitials in tuning ferromagnetism.
    Type of Medium: Online Resource
    ISSN: 0021-8979 , 1089-7550
    Language: English
    Publisher: AIP Publishing
    Publication Date: 2009
    detail.hit.zdb_id: 220641-9
    detail.hit.zdb_id: 3112-4
    detail.hit.zdb_id: 1476463-5
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  • 3
    In: Matter and Radiation at Extremes, AIP Publishing, Vol. 8, No. 5 ( 2023-09-01)
    Abstract: The first laser–plasma interaction experiment using lasers of eight beams grouped into one octad has been conducted on the Shenguang Octopus facility. Although each beam intensity is below its individual threshold for stimulated Brillouin backscattering (SBS), collective behaviors are excited to enhance the octad SBS. In particular, when two-color/cone lasers with wavelength separation 0.3 nm are used, the backward SBS reflectivities show novel behavior in which beams of longer wavelength achieve higher SBS gain. This property of SBS can be attributed to the rotation of the wave vectors of common ion acoustic waves due to the competition of detunings between geometrical angle and wavelength separation. This mechanism is confirmed using massively parallel supercomputer simulations with the three-dimensional laser–plasma interaction code LAP3D.
    Type of Medium: Online Resource
    ISSN: 2468-2047 , 2468-080X
    Language: English
    Publisher: AIP Publishing
    Publication Date: 2023
    detail.hit.zdb_id: 2858469-7
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  • 4
    In: Applied Physics Reviews, AIP Publishing, Vol. 8, No. 1 ( 2021-03-01)
    Abstract: Gas bubbles widely exist in nature and numerous industrial processes. The physicochemical characteristics of bubbles such as large specific surface area, low density, and hydrophobicity make them an ideal platform for developing colloidal and interfacial technologies. Over the past few decades, much effort has been devoted to investigating the properties and behaviors of bubbles and their applications. A series of bubble-based technologies (BBTs) have been developed, which have attracted increasing attention and shown great importance in a wide range of engineering, material, and biological fields. These BBTs, such as bubble flotation and the bubble-liposome system, provide feasible and promising solutions to mineral separation, material assembling, medical diagnosis, and drug delivery. In this work, we have systematically reviewed the physicochemical characteristics of bubbles and how to modulate their behaviors in complex fluid systems, as well as the underlying fundamental interaction mechanisms of bubbles in related BBTs. Advanced nanomechanical techniques such as atomic force microscopy, which are used to quantify the interaction mechanisms in bubble-containing systems, have been introduced. The effects of various influential factors on the bubble behaviors are discussed, which provide potential approaches to improve the controllability and performance of BBTs. The recent advances in the applications of selected BBTs in engineering, biomedical, and material areas are presented. Some remaining challenging issues and perspectives for future studies have also been discussed. This review improves the fundamental understanding of characteristics and surface interaction mechanisms of bubbles, with useful implications for developing advanced BBTs.
    Type of Medium: Online Resource
    ISSN: 1931-9401
    Language: English
    Publisher: AIP Publishing
    Publication Date: 2021
    detail.hit.zdb_id: 2265524-4
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  • 5
    In: APL Materials, AIP Publishing, Vol. 8, No. 1 ( 2020-01-01)
    Abstract: Magnetic Weyl semimetals (WSMs) bearing long-time seeking are still very rare. We have identified herein that EuCd2Sb2, a semimetal belonging to the type IV magnetic space group, hosts a magnetic exchange induced Weyl state via performing high magnetic field magnetotransport measurements and ab initio calculations. In the A-type antiferromagnetic structure, the external field larger than 3.2 T can align all Eu spins to be fully polarized along the c-axis and consequently drive EuCd2Sb2 into a spin polarized state. Magnetotransport measurements up to ∼55–60 T showed striking Shubnikov-de Hass oscillations associated with a nontrivial Berry phase. The ab initio calculations unveiled a phase transition of EuCd2Sb2 from a small gap antiferromagnetic topological insulator to a spin polarized WSM in which the Weyl points emerge along the Γ-Z path. Fermi arcs on (100) and (010) surfaces are also predicted. Meanwhile, the observed large anomalous Hall effect indicates the existence of Weyl points around the Fermi level. The results pave a way toward the realization of various topological states in a single material through the magnetic exchange manipulation.
    Type of Medium: Online Resource
    ISSN: 2166-532X
    Language: English
    Publisher: AIP Publishing
    Publication Date: 2020
    detail.hit.zdb_id: 2722985-3
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  • 6
    In: Matter and Radiation at Extremes, AIP Publishing, Vol. 4, No. 5 ( 2019-09-01)
    Abstract: We report experimental research on laser plasma interaction (LPI) conducted in Shenguang laser facilities during the past ten years. The research generally consists of three phases: (1) developing platforms for LPI research in mm-scale plasma with limited drive energy, where both gasbag and gas-filled hohlraum targets are tested; (2) studying the effects of beam-smoothing techniques, such as continuous phase plate and polarization smoothing, on the suppression of LPI; and (3) exploring the factors affecting LPI in integrated implosion experiments, which include the laser intensity, gas-fill pressure, size of the laser-entrance hole, and interplay between different beam cones. Results obtained in each phase will be presented and discussed in detail.
    Type of Medium: Online Resource
    ISSN: 2468-2047 , 2468-080X
    Language: English
    Publisher: AIP Publishing
    Publication Date: 2019
    detail.hit.zdb_id: 2858469-7
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  • 7
    In: Journal of Applied Physics, AIP Publishing, Vol. 108, No. 4 ( 2010-08-15)
    Abstract: The single crystals of tungsten bronze-type potassium lithium tantalate niobate doped with three concentrations erbium with good quality are grown using top-seed solution growth method. The unpolarized ultraviolet-visible-near infrared optical absorption spectra of these single crystals are measured at room temperature. The green and red upconversion emission properties are analyzed with respect to steady-state spectra and decay behaviors under 800 nm femtosecond laser excitation. The spectroscopic properties of Er3+ ions are studied on the basis of the Judd–Ofelt theory. 12 Er3+ ions absorption bands are observed ranging from 350 to 1650 nm, the lower limit is also the ultraviolet absorption edge of these crystals. The fluorescence branching ratio and radiative lifetime are calculated to support the upconversion mechanism. The relationship of the Judd–Ofelt parameters Ω4 & lt;Ω6 of Er3+ in these crystals is different from the general trend Ω2 & gt;Ω4 & gt;Ω6. Experimental results indicate that upconversion emission is a two-photon process. It follows that the shortening of lifetime and the increasing of intensities of red emission are due to the increase in Er3+ ions cluster sites. Excited state absorption and energy transfer processes lead to the green emission while cross relaxation process produces the red emission.
    Type of Medium: Online Resource
    ISSN: 0021-8979 , 1089-7550
    Language: English
    Publisher: AIP Publishing
    Publication Date: 2010
    detail.hit.zdb_id: 220641-9
    detail.hit.zdb_id: 3112-4
    detail.hit.zdb_id: 1476463-5
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  • 8
    Online Resource
    Online Resource
    AIP Publishing ; 2000
    In:  Journal of Applied Physics Vol. 87, No. 9 ( 2000-05-01), p. 5535-5537
    In: Journal of Applied Physics, AIP Publishing, Vol. 87, No. 9 ( 2000-05-01), p. 5535-5537
    Abstract: The effects of anisotropy axes distribution on the properties of longitudinal recording media are simulated using the micromagnetic modeling. The angle between the anisotropy axis and the preferred direction is assumed to follow the Gaussian distribution. Hysteresis loops are simulated with the field applied in the preferred direction and perpendicular to it. Orientation ratios (OR) are calculated for different anisotropy distribution. OR (coercivity) increased from 1.4 to 79.2 when standard deviation of anisotropy distribution σ decreased from 0.7 to 0.05. The effect of the anisotropy distribution on the recording performance is evaluated, too. The results show that narrowing the anisotropy distribution will increase the OR and decrease the transition noise power and transition length. It was found that a critical point occurred at σ=0.15, below which the OR can be maintained at a sufficiently high value and yet the integrated noise power can be kept low.
    Type of Medium: Online Resource
    ISSN: 0021-8979 , 1089-7550
    Language: English
    Publisher: AIP Publishing
    Publication Date: 2000
    detail.hit.zdb_id: 220641-9
    detail.hit.zdb_id: 3112-4
    detail.hit.zdb_id: 1476463-5
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  • 9
    Online Resource
    Online Resource
    AIP Publishing ; 2006
    In:  Applied Physics Letters Vol. 89, No. 25 ( 2006-12-18)
    In: Applied Physics Letters, AIP Publishing, Vol. 89, No. 25 ( 2006-12-18)
    Abstract: The electrical conductivity of P-doped ZnO can be controlled by changing the P-doping concentration. With increasing P concentration, ZnO can be changed from n type to p type. At the same time, a redshift of the band gap energy is observed by using the photoluminescence spectroscopy and UV-visible spectrophotometer. X-ray diffraction results show that lattice spacings of ZnO increase with P concentration, which indicates that P substitutes O, and this leads to a lattice spacing increase and an optical band gap energy decrease.
    Type of Medium: Online Resource
    ISSN: 0003-6951 , 1077-3118
    RVK:
    Language: English
    Publisher: AIP Publishing
    Publication Date: 2006
    detail.hit.zdb_id: 211245-0
    detail.hit.zdb_id: 1469436-0
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  • 10
    In: Applied Physics Letters, AIP Publishing, Vol. 90, No. 14 ( 2007-04-02)
    Abstract: Microphotoluminescence (μ-PL) of high-aspect-ratio Si nanopillars fabricated by etching Ni-nanodot∕SiO2 masked Si substrate is investigated. The 320-nm-tall Si nanopillars obtained by CF4∕Ar mixed inductively coupled-plasma reactive ion etching process with density of 2.8×1010cm−2 further shrink size from 30to6nm by oxidation and etching. Blue-green μ-PL with two decomposed wavelengths at 425 and 475nm is attributed to oxygen-related defects on the oxidized Si nanopillar surface. Defect-related near-infrared PL at 703 and 740nm remains unchanged, while a quantum-confinement-effect-dependent PL blueshifted from 874to826nm as the Si nanopillar size reduces from 7.2to6.0nm is preliminarily observed.
    Type of Medium: Online Resource
    ISSN: 0003-6951 , 1077-3118
    RVK:
    Language: English
    Publisher: AIP Publishing
    Publication Date: 2007
    detail.hit.zdb_id: 211245-0
    detail.hit.zdb_id: 1469436-0
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