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  • 1
    In: Physics of Plasmas, AIP Publishing, Vol. 21, No. 5 ( 2014-05-01)
    Abstract: Imploding wire arrays on the 20 MA Z generator have recently provided some of the most powerful and energetic laboratory sources of multi-keV photons, including ∼375 kJ of Al K-shell emission (hν ∼ 1–2 keV), ∼80 kJ of stainless steel K-shell emission (hν ∼ 5–9 keV) and a kJ-level of Mo K-shell emission (hν ∼ 17 keV). While the global implosion dynamics of these different wire arrays are very similar, the physical process that dominates the emission from these x-ray sources fall into three broad categories. Al wire arrays produce a column of plasma with densities up to ∼3 × 1021 ions/cm3, where opacity inhibits the escape of K-shell photons. Significant structure from instabilities can reduce the density and increase the surface area, therefore increase the K-shell emission. In contrast, stainless steel wire arrays operate in a regime where achieving a high pinch temperature (achieved by thermalizing a high implosion kinetic energy) is critical and, while opacity is present, it has less impact on the pinch emissivity. At higher photon energies, line emission associated with inner shell ionization due to energetic electrons becomes important.
    Type of Medium: Online Resource
    ISSN: 1070-664X , 1089-7674
    Language: English
    Publisher: AIP Publishing
    Publication Date: 2014
    detail.hit.zdb_id: 1472746-8
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  • 2
    In: Review of Scientific Instruments, AIP Publishing, Vol. 94, No. 4 ( 2023-04-01)
    Abstract: We describe the first implementation of a Josephson Traveling Wave Parametric Amplifier (JTWPA) in an axion dark matter search. The operation of the JTWPA for a period of about two weeks achieved sensitivity to axion-like particle dark matter with axion–photon couplings above 10−13 Ge V−1 over a narrow range of axion masses centered around 19.84 µeV by tuning the resonant frequency of the cavity over the frequency range of 4796.7–4799.5 MHz. The JTWPA was operated in the insert of the axion dark matter experiment as part of an independent receiver chain that was attached to a 0.56-l cavity. The ability of the JTWPA to deliver high gain over a wide (3 GHz) bandwidth has engendered interest from those aiming to perform broadband axion searches, a longstanding goal in this field.
    Type of Medium: Online Resource
    ISSN: 0034-6748 , 1089-7623
    Language: English
    Publisher: AIP Publishing
    Publication Date: 2023
    detail.hit.zdb_id: 209865-9
    detail.hit.zdb_id: 1472905-2
    SSG: 11
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  • 3
    In: The Journal of Chemical Physics, AIP Publishing, Vol. 147, No. 16 ( 2017-10-28)
    Abstract: The development of Li-ion batteries for energy storage has received significant attention. The synthesis and characterization of electrolytes in these batteries are an important component of this development. Ionic liquids (ILs) have been proposed as possible electrolytes in these devices. Thus, the accurate determination of thermophysical properties for these solvents becomes important for determining their applicability as electrolytes. In this contribution, we present the synthesis and experimental/computational characterization of thermodynamic and transport properties of a pyrrolidinium based ionic liquid as a first step to investigate the possible applicability of this class of ILs for Li-ion batteries. A quantum mechanical-based force field with many-body polarizable interactions has been developed for the simulation of spirocyclic pyrrolidinium, [sPyr+], with BF4− and Li+. Molecular dynamics calculations employing intra-molecular polarization predicted larger heat of vaporization and self-diffusion coefficients and smaller densities in comparison with the model without intra-molecular polarization, indicating that the inclusion of this term can significantly effect the inter-ionic interactions. The calculated properties are in good agreement with available experimental data for similar IL pairs and isothermal titration calorimetry data for [sPyr+] [BF4−].
    Type of Medium: Online Resource
    ISSN: 0021-9606 , 1089-7690
    Language: English
    Publisher: AIP Publishing
    Publication Date: 2017
    detail.hit.zdb_id: 3113-6
    detail.hit.zdb_id: 1473050-9
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  • 4
    Online Resource
    Online Resource
    AIP Publishing ; 2021
    In:  The Journal of Chemical Physics Vol. 154, No. 8 ( 2021-02-28)
    In: The Journal of Chemical Physics, AIP Publishing, Vol. 154, No. 8 ( 2021-02-28)
    Abstract: Binary mixtures of fully flexible linear tangent chains composed of bonded Lennard-Jones interaction sites (monomers) were studied using the molecular dynamics simulation in the NVT ensemble. Their interfacial properties were investigated in planar interfaces by direct simulation of an explicit liquid film in equilibrium with its vapor. A method for the calculation of long-range interactions in inhomogeneous fluids was implemented to take into account the potential truncation effects. Surface tension and the pressure tensor were calculated via the classical Irving–Kirkwood method; vapor pressure, orthobaric densities, density profiles, and Gibbs relative adsorption of the volatile component with respect to the heavy component were also obtained. The properties were studied as a function of the temperature, molar concentration of the heavy component, and the asymmetry of the mixture. According to the results of this work, the temperature loses influence on the surface tension, vapor pressure, and Gibbs relative adsorption curves as the molecular length of the heavy component increases. This suggests that the universal behavior observed in pure fluids of Lennard-Jones chains also holds for binary mixtures. The contribution of the long-range interactions turned out to account for about 60%, 20%, and 10% of the surface tension, vapor pressure, and orthobaric density final values, respectively. This contribution was even larger at high temperatures and for large molecules. Strong enrichment of the volatile component at the interface was observed in the asymmetric mixtures. One of these mixtures even showed a barotropic effect at elevated pressures and a class III phase behavior.
    Type of Medium: Online Resource
    ISSN: 0021-9606 , 1089-7690
    Language: English
    Publisher: AIP Publishing
    Publication Date: 2021
    detail.hit.zdb_id: 3113-6
    detail.hit.zdb_id: 1473050-9
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  • 5
    Online Resource
    Online Resource
    AIP Publishing ; 2015
    In:  The Journal of Chemical Physics Vol. 143, No. 4 ( 2015-07-28)
    In: The Journal of Chemical Physics, AIP Publishing, Vol. 143, No. 4 ( 2015-07-28)
    Abstract: A new method to account for long range electrostatic contributions is proposed and implemented for quantum mechanics/molecular mechanics long range electrostatic correction (QM/MM-LREC) calculations. This method involves the use of the minimum image convention under periodic boundary conditions and a new smoothing function for energies and forces at the cutoff boundary for the Coulomb interactions. Compared to conventional QM/MM calculations without long-range electrostatic corrections, the new method effectively includes effects on the MM environment in the primary image from its replicas in the neighborhood. QM/MM-LREC offers three useful features including the avoidance of calculations in reciprocal space (k-space), with the concomitant avoidance of having to reproduce (analytically or approximately) the QM charge density in k-space, and the straightforward availability of analytical Hessians. The new method is tested and compared with results from smooth particle mesh Ewald (PME) for three systems including a box of neat water, a double proton transfer reaction, and the geometry optimization of the critical point structures for the rate limiting step of the DNA dealkylase AlkB. As with other smoothing or shifting functions, relatively large cutoffs are necessary to achieve comparable accuracy with PME. For the double-proton transfer reaction, the use of a 22 Å cutoff shows a close reaction energy profile and geometries of stationary structures with QM/MM-LREC compared to conventional QM/MM with no truncation. Geometry optimization of stationary structures for the hydrogen abstraction step by AlkB shows some differences between QM/MM-LREC and the conventional QM/MM. These differences underscore the necessity of the inclusion of the long-range electrostatic contribution.
    Type of Medium: Online Resource
    ISSN: 0021-9606 , 1089-7690
    Language: English
    Publisher: AIP Publishing
    Publication Date: 2015
    detail.hit.zdb_id: 3113-6
    detail.hit.zdb_id: 1473050-9
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  • 6
    Online Resource
    Online Resource
    AIP Publishing ; 2012
    In:  Journal of Physical and Chemical Reference Data Vol. 41, No. 2 ( 2012-06-01), p. 023102-023102-11
    In: Journal of Physical and Chemical Reference Data, AIP Publishing, Vol. 41, No. 2 ( 2012-06-01), p. 023102-023102-11
    Abstract: A wide-ranging correlation for the viscosity surface of sulfur hexafluoride (SF6) has been developed that incorporates generalized friction theory (GFT). The approach requires, as the core thermodynamic model, a reference-quality equation of state (EoS). Here the EoS of Guder and Wagner has been selected for that purpose. All available experimental data, to the extent of our knowledge, were considered in the development of the model. The correlation performs best in the low-pressure (less than 0.33 MPa) region from 300 K to 700 K where the estimated uncertainty (considered to be combined expanded uncertainty with a coverage factor of two) is 0.3%. In the region from 300 K to 425 K for pressures less than 20 MPa, the estimated uncertainty is less than 1%. Where there were data available for validation at temperatures from 230 K to 575 K for pressures up to 50 MPa, the estimated uncertainty is 2%. The correlation extrapolates in a physically reasonable manner and may be used at pressures to 100 MPa and temperatures from the triple point to 1000 K.
    Type of Medium: Online Resource
    ISSN: 0047-2689 , 1529-7845
    Language: English
    Publisher: AIP Publishing
    Publication Date: 2012
    detail.hit.zdb_id: 2006308-8
    SSG: 11
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  • 7
    In: Journal of Applied Physics, AIP Publishing, Vol. 134, No. 8 ( 2023-08-28)
    Abstract: In this work, we report on the development and application of a simple reflectivity technique for real-time monitoring of the fabrication of porous-silicon multilayers. The technique allows for high-resolution quantification of the effective optical thickness of the layers during the fabrication process, enabling calibration of attack rates and detection of changes in porosity. Our experiments revealed that the porosity of the layers increases during the attack, indicating incomplete passivation of the pores. By studying thin porous-silicon layers in the absence of applied current, we developed a three-layer model to understand passive chemical etching. Furthermore, our study allowed discrimination between the two mechanisms responsible for the reduction of effective optical thickness with time, with changes in porosity being the dominant one. The technique has the potential to enable real-time control of multilayer fabrication, offering flexibility in controlling environmental conditions and silicon wafer conduction properties. Our results contribute to the understanding of multilayer fabrication and reflectivity-based process monitoring.
    Type of Medium: Online Resource
    ISSN: 0021-8979 , 1089-7550
    Language: English
    Publisher: AIP Publishing
    Publication Date: 2023
    detail.hit.zdb_id: 220641-9
    detail.hit.zdb_id: 3112-4
    detail.hit.zdb_id: 1476463-5
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  • 8
    Online Resource
    Online Resource
    AIP Publishing ; 1966
    In:  Review of Scientific Instruments Vol. 37, No. 5 ( 1966-05-01), p. 673-673
    In: Review of Scientific Instruments, AIP Publishing, Vol. 37, No. 5 ( 1966-05-01), p. 673-673
    Type of Medium: Online Resource
    ISSN: 0034-6748 , 1089-7623
    Language: English
    Publisher: AIP Publishing
    Publication Date: 1966
    detail.hit.zdb_id: 209865-9
    detail.hit.zdb_id: 1472905-2
    SSG: 11
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  • 9
    In: Journal of Renewable and Sustainable Energy, AIP Publishing, Vol. 8, No. 4 ( 2016-07-01)
    Abstract: Energy systems with renewable sources are used around the world in order to satisfy both off-grid and on-grid load demands, and are commonly coupled to conventional sources. A good behavior of this kind of systems depends on the renewable sources availability that includes the solar irradiance and the wind speed, as well as the profile variations over the energy demand. Their main objective is to satisfy the load demand while minimizing the use of conventional sources, reducing pollutant emissions and storing the energy excess for deficit conditions. This paper presents modeling, neural forecasting and optimal sizing for hybrid energy systems, which are proposed to minimize both the overall annual cost and the use of conventional sources, which in turn represents reduction of pollutant emissions. In this paper, the use of renewable sources along with load demand variations are predicted by a High Order Neural Network trained with an Extended Kalman Filter, whereas the optimal sizing is calculated by using both a Clonal Selection Algorithm and a Genetic Algorithm. The efficiency of using neural forecasting data is illustrated through a simulation with the results showing the effectiveness of both optimization algorithms for calculating an optimal sizing of the hybrid system, which ultimately represents an optimal cost-effective system.
    Type of Medium: Online Resource
    ISSN: 1941-7012
    Language: English
    Publisher: AIP Publishing
    Publication Date: 2016
    detail.hit.zdb_id: 2444311-6
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