In:
The Journal of Chemical Physics, AIP Publishing, Vol. 20, No. 12 ( 1952-12-01), p. 1949-1954
Abstract:
Raman displacements, semiquantitative relative intensities, and quantitative depolarization factors for liquid chlorodibromomethane and deuterochlorodibromomethane, and infrared wave numbers and percent transmission curves for both the liquid and gaseous states in the region 400–4300 cm−1 were obtained and compared with previous data. A normal coordinate treatment (Wilson FG matrix method) was carried out, and a consistent set of potential constants for both molecules was determined, using a potential energy function containing all possible 2nd degree terms. Assignments were made for all observed bands. The heat content, free energy, entropy, and heat capacity at constant pressure were calculated for 12 temperatures from 100° to 1000°K.
Type of Medium:
Online Resource
ISSN:
0021-9606
,
1089-7690
Language:
English
Publisher:
AIP Publishing
Publication Date:
1952
detail.hit.zdb_id:
3113-6
detail.hit.zdb_id:
1473050-9
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