In:
Journal für Praktische Chemie, Wiley, Vol. 26, No. 3-4 ( 1964-11), p. 140-146
Abstract:
Ultrasonic waves obtained from M ULLARD 's high frequency ultrasonic generator type E‐7562 with a barium titanate transducer having a frequency of I Mc./sec. were employed to study the sonochemical decomposition of aqueous bromoform solution. At constant R. F. output (about 1.7 Kv) to the crystal, the reaction was found to obey the Zero‐order kinetics with average velocity constants in standard unit as follows: Effects of bulk and ultrasonic intensity have also been demonstrated. The rate of reaction at different dilutions of aqueous bromoform solution and also at different intensities has been investigated conductometrically. A probable mechanism of the reaction was also presented.
Type of Medium:
Online Resource
ISSN:
0021-8383
DOI:
10.1002/prac.v26:3/4
DOI:
10.1002/prac.19640260306
Language:
English
Publisher:
Wiley
Publication Date:
1964
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1100305-4
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2041384-1
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2749086-5
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2995-6
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2033084-4
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