In:
Zeitschrift für anorganische und allgemeine Chemie, Wiley, Vol. 328, No. 3-4 ( 1964-04), p. 144-153
Abstract:
Aminolysis of AsCl 3 or transamination of As(NMe 2 ) 3 with methyl amine, n‐butyl amine, and iso‐propyl amine yields the alkylimino‐arsanes As 4 (NMe) 6 , As 4 (N‐i‐Pr) 6 , and As 4 (N‐n‐Bu) 6 having an adamantane‐like structure. Contrary to these results is the aminolysis of AsCl 3 by tert.‐butyl amine, which gives tert.‐butylamino‐tert.‐butyl‐imino‐arsane (t‐BuNHAs‐N‐t‐Bu) 2 . Selective cleavage of the As‐X‐bonds in As 4 (NMe) 6 by HCl leads to As 4 (NMe) 5 Cl 2 or (MeNAsCl) 3 . With CS 2 , exchange of sulfur for RN groups in As 4 (NR) 6 (R = Me, n‐Bu) occurs with formation of alkyl‐isothiocyanates and alkylimino‐arsenic sulfides.
Type of Medium:
Online Resource
ISSN:
0044-2313
,
1521-3749
DOI:
10.1002/zaac.v328:3/4
DOI:
10.1002/zaac.19643280305
Language:
English
Publisher:
Wiley
Publication Date:
1964
detail.hit.zdb_id:
201094-X
detail.hit.zdb_id:
1481139-X
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