ISSN:
0030-4921
Keywords:
Chemistry
;
Analytical Chemistry and Spectroscopy
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Small discrepancies between 3H and 1H chemical shifts in organic compounds led to the finding that the ratio of Larmor frequencies ωT/ωH depends on the carbon-hydrogen bond hybridisation. The ‘best’ ratio for ghost referencing of 3H NMR spectra was then determined from measurements on purified partially tritiated TMS as 1.066639738±2 × 10-9. Some 3H isotope effects on chemical shifts are listed and the 3H isotope effect on the methylene geminal coupling constant in benzyl methyl sulphoxide is measured. Use of 2H in the measurement of 2J(HH) coupling constants has inherent disadvantages, overcome by use of 3H substitution.
Additional Material:
2 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/mrc.1270121006
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