In:
Helvetica Chimica Acta, Wiley, Vol. 58, No. 1 ( 1975-01), p. 1-13
Abstract:
1 H—NMR. has been used to study the chemistry of the hydroxyethyliminodiacetate complexes of praseodymium in aqueous solution. The ligand exchanges by spontaneous dissociation of the metal‐bis‐hydroxyethyliminodiacetate (1:2 complex) and of the metal‐bis‐hydroxyethyliminodiacetate hydroxocomplex, by acid catalysed dissociation of the 1:2 complex, and by a bimolecular process involving the free ligand and the 1:2 complex or the ternary hydroxo‐complex. The ligand exchange rate constants are given and the mechanisms discussed.
Type of Medium:
Online Resource
ISSN:
0018-019X
,
1522-2675
DOI:
10.1002/hlca.19750580102
Language:
English
Publisher:
Wiley
Publication Date:
1975
detail.hit.zdb_id:
74-7
detail.hit.zdb_id:
1475013-2
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