In:
Acta Physica Sinica, Acta Physica Sinica, Chinese Physical Society and Institute of Physics, Chinese Academy of Sciences, Vol. 33, No. 1 ( 1984), p. 110-
Abstract:
As a natural extension of work [4], in this paper the calculation of zero field splitting parameter D of 3d5 ions in low symmetry ( C4v or D4h,C3v or D3h ) crystal field is discussed. The expressions of parameter D in terms of Racah parameters, crystal field parameters and spin-orbit coupling constant ξ are obtained. Applying to Fe3+ in α -Al2O3 crystal, the calculated result agrees fairly well with the experimental value.
Type of Medium:
Online Resource
ISSN:
1000-3290
,
1000-3290
Language:
Unknown
Publisher:
Acta Physica Sinica, Chinese Physical Society and Institute of Physics, Chinese Academy of Sciences
Publication Date:
1984
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