In:
The Journal of Chemical Physics, AIP Publishing, Vol. 76, No. 7 ( 1982-04-01), p. 3371-3377
Abstract:
The infrared and Raman spectra of ClF in solution in liquid Ar, O2, and N2 are reported. The line profile evolution with temperature has been analyzed from the point of view of molecular dynamics, using the Fischer–Laubereau model for the Raman isotropic lines, and the Frenkel–Rakov, Debye, Gordon, and Bartoli–Litovitz models for the IR spectra. Spectroscopic data are discussed using these models in terms of Lennard-Jones ClF-X interaction potentials for binary mixtures (X = Ar, O2, N2). An unexpected behavior of N2 is pointed out from spectra of ternary ClF–N2–X mixtures (X = Ar, O2).
Type of Medium:
Online Resource
ISSN:
0021-9606
,
1089-7690
Language:
English
Publisher:
AIP Publishing
Publication Date:
1982
detail.hit.zdb_id:
3113-6
detail.hit.zdb_id:
1473050-9
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