In:
Acta Physica Sinica, Acta Physica Sinica, Chinese Physical Society and Institute of Physics, Chinese Academy of Sciences, Vol. 33, No. 4 ( 1984), p. 523-
Abstract:
In this paper, the structure of glasses in Li2O(LiCl)2B2O3-Al2O3 system, particularly the influence of Al2O3, is investigated by Raman spectra. For Li2O-B2O3 glasses, with increasing Li2O content, triangular BO3 units change into BO4 tetrahedra and borate groups containing more BO4 are formed. When Li2O content is greater than 35 mol% the metaborate groups begin to form. By replacing B2O3 with Al2O3, the Al3+ ions introduced in glasses take the four-coordination, and AlO4 tetrahedra replace BO4 tetrahedra under the condition of existing sufficient Li2O. However, when Al2O3/Li2O ratio is close to or even greater than unity, part of Al3+ ions are no more in the four-coordination. The experiment also indicates that Raman spectra only depends upon the O/B/Al ratio, showing that the LiCI molecules introduced into the glass are dissociated by glass network. These results can be used to interprete the variations of ionic conductivity with composition.
Type of Medium:
Online Resource
ISSN:
1000-3290
,
1000-3290
Language:
Unknown
Publisher:
Acta Physica Sinica, Chinese Physical Society and Institute of Physics, Chinese Academy of Sciences
Publication Date:
1984
Permalink