In:
Canadian Journal of Physics, Canadian Science Publishing, Vol. 60, No. 9 ( 1982-09-01), p. 1288-1302
Abstract:
The analysis of two parallel absorption bands of NO 2 , at 13 400 and 13 200 cm −1 respectively, has been performed using high resolution Fourier transform spectra. This paper is an extension of the work performed on the 7390 Å band (13 500 cm −1 ) in 1977 by Hallin and Merer, and completed in 1980 by Perrin, Camy-Peyret, Flaud, and Luc.The lines involving the K a = 0, 1, 2, 3, 4 stacks for the 13 400 cm −1 band and K a = 0, 1, 3, 4 for the 13 200 cm −1 band have been assigned and considerable spin–orbit and/or Coriolis coupling induced transitions have been detected.The 13 400 cm −1 band can be considered as belonging to the [Formula: see text] electronic transition, while the 13 200 cm −1 band might be, as the 7390 Å band (at 13 500 cm −1 ), a transition within the ground state manifold which barrows its intensity through vibronic coupling from the 13 400 cm −1 band. Tentative vibrational assignments are given.
Type of Medium:
Online Resource
ISSN:
0008-4204
,
1208-6045
Language:
English
Publisher:
Canadian Science Publishing
Publication Date:
1982
detail.hit.zdb_id:
2990-7
detail.hit.zdb_id:
2021497-2
Permalink