In:
Helvetica Chimica Acta, Wiley, Vol. 67, No. 3 ( 1984-05-02), p. 876-884
Abstract:
Pure pencillin N α‐sulfoxide ( 1 ) and penicillin N β‐sulfoxide ( 2 ) were obtained by HPLC and tested as substrates for deacetoxycephalosporin C synthetase (DXCS). Neither one of the sulfoxides was utilized under conditions of conversion of penicillin N ( 8 ) to deacetoxycephalosporin C ( 9 ). The cephalosporin C α and β‐sulfoxides ( 3 and 4 , resp.) were also prepared. Relative stabilities of the sulfoxides 3 and 4 are discussed by interpretation of the 13 C‐NMR spectra.
Type of Medium:
Online Resource
ISSN:
0018-019X
,
1522-2675
DOI:
10.1002/hlca.19840670329
Language:
English
Publisher:
Wiley
Publication Date:
1984
detail.hit.zdb_id:
74-7
detail.hit.zdb_id:
1475013-2
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