In:
Zeitschrift für Naturforschung A, Walter de Gruyter GmbH, Vol. 39, No. 9 ( 1984-9-1), p. 846-852
Abstract:
The rate constant of the reaction NH 2 +CH 4 →NH 3 +CH 3 was measured at temperatures of about 1800 K by time-resolved UV-spectroscopy of the products behind incident shock waves. NH 2 was produced by the presence and thermal decomposition of hydrazine. The data were evaluated by fitting simulated concentration-time-profiles to the measured ones. A mean rate constant k = (4±2) 10 11 cm 3 mol -1 s -1 1730 〈 T/K 〈 1950 was obtained. The temperature dependence of the reaction is discussed.
Type of Medium:
Online Resource
ISSN:
1865-7109
,
0932-0784
DOI:
10.1515/zna-1984-0904
Language:
English
Publisher:
Walter de Gruyter GmbH
Publication Date:
1984
detail.hit.zdb_id:
2079610-9
detail.hit.zdb_id:
124634-3
detail.hit.zdb_id:
124633-1
detail.hit.zdb_id:
2767412-5
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