In:
Collection of Czechoslovak Chemical Communications, Institute of Organic Chemistry & Biochemistry, Vol. 53, No. 9 ( 1988), p. 1902-1909
Abstract:
A time-independent Green function formalism is developed to study the excess energy dependence on the nonradiative decay in the S 1 state of benzene. Effects of purely electronic relaxation (internal conversion, IC) and intramolecular vibrational redistribution, IVR, are taken into account at the same time. Model calculations show that the drastic increase in the nonradiative decay rate at around 3 000 cm -1 excess energy is due to the same onset of both IC and IVR rates. Our theory can explain the difference in rate constant between IVR and IC observed by Moss and Parmenter.
Type of Medium:
Online Resource
ISSN:
0010-0765
,
1212-6950
DOI:
10.1135/cccc19881902
Language:
English
Publisher:
Institute of Organic Chemistry & Biochemistry
Publication Date:
1988
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