ISSN:
1600-5759
Source:
Crystallography Journals Online : IUCR Backfile Archive 1948-2001
Topics:
Chemistry and Pharmacology
,
Geosciences
,
Physics
Notes:
The structure of the first metal compound of pyridyl N,N′-coordinated di-2-pyridyl ketone oxime (dpk-o), fac-tricarbonylchloro(di-2-pyridyl-κN ketone oxime)rhenium(I) dimethyl sulfoxide solvate, [ReCl(C11H9N2O)(CO)3]·C2H6OS, (I), is reported. The coordinated atoms (two N atoms from the pyridyl rings, three C atoms from the carbonyl groups and one Cl atom) are in a distorted octahedral arrangement, with the major distortion being due to the constraints associated with the binding of dpk-o. The packing of the molecules shows antiparallel tapes of (I), with a network of classical (O...H—O) and non-classical (O...H—C) hydrogen bonds between the dimethyl sulfoxide solvate molecule and the complexed metal moiety.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1107/S0108270101009593
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