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  • 1990-1994  (2)
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  • 1
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 92 (1990), S. 5144-5154 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: Using the scanning simulation method we study the tricritical behavior at the Flory θ-point of self-avoiding walks (SAWs) with nearest neighbors attractions ε (ε〈0) on a simple cubic lattice (in the following paper we investigate tricritical trails on the same lattice). The tricritical temperature Tt is −ε/kBTt=0.274±0.006 (one standard deviation). The results for the radius of gyration G and the end-to-end distance R are consistent with the theoretical prediction νt=0.5 and with a logarithmic correction to scaling; the ratio G2/R2 =0.1659±0.0001 (calculated without taking into account correction to scaling) is only slightly smaller than the theoretical asymptotic value 1/6=0.1666.... The results for the partition function Z at Tt lead to γt=1.005±0.017 in accord with theory and to μt=5.058±0.014, where μt is the growth parameter; the correction to scaling in Z is found to be relatively small. For the chain length studied the divergence of the specific heat at Tt (αt(approximately-equal-to)0.3) is significantly larger than that predicted by theory, (ln N)3/11 (i.e., αt=0). Also, at Tt our data are affected by strong correction to scaling and are thus not consistent with the theoretical value of the crossover exponent φt=0.5.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 92 (1990), S. 5155-5161 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: A self-attracting trail is a walk on a lattice which may intersect itself but two bonds are not allowed to overlap; an interaction energy ε (ε〈0) is associated with each self-intersection. Using the scanning simulation method, we study the tricritical behavior at the collapse transition of self-attracting trails of N≤250 steps on a simple cubic lattice. In the preceding paper (paper I) tricritical self-avoiding walks (SAWs) on the same lattice have been investigated. The tricritical temperature of trails is −ε/kBTt=0.550±0.004 (one standard deviation). The results for the radius of gyration, G, and the end-to-end distance, R, lead to νt=0.515±0.003, which is larger than νt=1/2, the theoretical prediction for SAWs. The ratio G2/R2=0.1676±0.0001 is slightly larger than 1/6=0.1666 ... predicted by theory for SAWs; The results for the partition function at Kt lead to γt=1.040±0.005 (as compared to the theoretical prediction for SAWs γt=1) and to the growth parameter value μt=5.0023±0.0020. The crossover exponent, φt, is approximately 0.5 as expected for SAWs at tricriticality; this value is significantly smaller than that found for SAWs in paper I. The results of G, R, and Z at Kt are found to be inconsistent with logarithmic corrections to scaling. However, we do not think that the above differences between trails and SAWs are sufficient to suggest unequivocally that the two models belong to different universality classes.
    Type of Medium: Electronic Resource
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