In:
Chemische Berichte, Wiley, Vol. 126, No. 10 ( 1993-10), p. 2255-2257
Abstract:
Synthesis, Structure, and Rearrangement of Chlorobis(2,4,6‐tri‐ tert ‐butylphenyl)gallane The title compound 1 is easily obtained from GaCl 3 and 2 equvialents of supermesityllithium. According to an X‐ray structure analysis one of the supermesityl rings shows a large deviation from planarity. Heating of 1 in vacuo gives mainly two products: an isomer of 1 in which one of the supermesityl groups is bound to Ga by one of its tert ‐butyl groups ( 2 ) and a benzo[ b ]gallolane ( 3 ) formed by elimination of HCl, X‐ray structure analyses and full NMR ( 1 H, 13 C) data are provided for 1 and 2 , MS and characteristic NMR ( 1 H, 13 C) data for 3 .
Type of Medium:
Online Resource
ISSN:
0009-2940
DOI:
10.1002/cber.v126:10
DOI:
10.1002/cber.19931261014
Language:
English
Publisher:
Wiley
Publication Date:
1993
detail.hit.zdb_id:
1475009-0
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