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Equilibrium constants for the formation of Cu(I) halide complexes (1990)

Sharma, Virender K. ; Millero, Frank J.

Springer

Journal of solution chemistry 19 (1990), S. 375-390

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ISSN: 1572-8927

Keywords: Equilibrium constants ; CuCl ; CuBr ; complexes ; Pitzer equations ; spectral data

Source: Springer Online Journal Archives 1860-2000

Topics: Chemistry and Pharmacology

Notes: Abstract The stoichiometric equilibrium constants, K 3 * , for the formation of CuX 3 2− from CuX 2 − +X− where X=Cl and Br, have been determined from spectral measurements. The measurements were made in NaCl and NaBr solutions from I=0.5 to 6.0m at 5, 25 and 45°C. The measured constants were extrapolated to infinite dilution using the Pitzer equations. The Pitzer parameters, β0, β1 and Cφ, for the interaction of Na+ with CuX 2 − and CuX 3 2− are briefly discussed.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1007/BF00648142

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