ISSN:
0030-493X
Keywords:
Chemistry
;
Analytical Chemistry and Spectroscopy
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Interesting oxygen transfers from the o-nitro group to allenic carbons were observed in allenyl o-nitrophenyl sulphides under electron impact conditions giving rise to abundant fragment ions at m/z 151, 138 and 136. However, a similar oxygen transfer to the sulphur leads to another intense ion at m/z 145. The proposed fragmentation pathways and the ion structures were established through high-resolution data, collision-activated dissociation mass-analysed ion kinetic energy and B/E linked-scan spectra.
Additional Material:
3 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/oms.1210270425
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