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  • 1995-1999  (2)
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  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Environmental geology 30 (1997), S. 224-230 
    ISSN: 1432-0495
    Keywords: Key words Sediment ; Washington ; DC ; Pollution ; phosphorus ; nutrients
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Notes: Abstract  Sediments in the rivers and basins around Washington, DC, have high concentrations of phosphorus, which, based on geographic distributions, is largely derived from urban runoff and municipal sewage. Dissolved-particulate phosphate exchange reactions and biological uptake of dissolved phosphorus from the water column may be an added source of phosphorus to the sediments. Concentrations of total sedimentary phosphorus ranged from 24 to 56 μm P/g-dw, and were highest in areas near combined sewer outfalls. As a part of this study, sedimentary phosphorus was fractionated into Fe-P, Ca-P, Al-P, and organic phases using a selective-sequential leaching procedure. The distribution of the phases in all sediments analyzed follow the order , Fe-P〉Ca-P〉Al-P. Spatial variations in the amounts of phosphorus in the different phases is related to the sources of phosphorus to the area. The proportions of occluded Al-P and organic P are 10–20% of the total P, respectively. This suggests that phosphorus from natural sources is small compared to anthropogenic inputs in this area. The high leachable Fe-P and Ca-P in these sediments might contribute a substantial amount of P to the water column under conditions of remobilization.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    Journal of radioanalytical and nuclear chemistry 236 (1998), S. 261-266 
    ISSN: 1588-2780
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Compton suppression gamma-spectroscopy provides an efficient method for measuring the concentration of226Ra,228Ra, and210Pb in ocean sediments. The background reduction realized from the suppressed mode of operation provides an “active shield” to allow for the low-level counting required for these measurements. We have used the method to study the possible accumulation of radium from produced waters in sediments from Gulf of Mexico sites of varied distances from drill platforms. In addition,210Pb levels were determined to evaluate the use of our spectrometer for this purpose. Baseline undisturbed concentrations have been obtained from the study of subsurface core material which predates drilling activities. Correlations of radium isotope concentrations with iron and barium provide information concerning the possible relationships between radium levels and drilling activity (excess barium) and natural variations in sediment texture (iron).
    Type of Medium: Electronic Resource
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