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  • 1995-1999  (13)
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  • 1
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 82 (1997), S. 5460-5464 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Microstructural reactions of PdGe ohmic contact to n-type GaAs were investigated using x-ray diffraction, Auger electron spectroscopy, and slow positron beam. The results were compared with electrical properties to interpret the ohmic contact formation mechanism for the Ge/Pd/n-type GaAs system. The lowest contact resistance of 1.7 Ω mm and the formation of a PdGe compound are observed at the annealing temperature of 240 °C. Slow positron beam results show that Ga vacancies are produced below PdGe during the formation of PdGe ohmic contact to n-type GaAs. This means the existence of n+-GaAs layer below PdGe because Ga vacancy concentration increases with n-type impurity concentration. This supports that the n+-GaAs layer is a regrown layer decomposed from PdxGaAs containing excess Ge atoms during annealing. © 1997 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 82 (1997), S. 5011-5016 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: The thermal stability of Ti/Pt/Au Schottky gates on high-low doped GaAs metal–semiconductor field-effect transistors (MESFETs) was investigated in the temperature range of 300–500 °C, using current–voltage and capacitance–voltage measurements and cross-sectional transmission electron microscopy with energy dispersive x-ray spectroscopy. At annealing temperatures 〉350 °C, the interfacial reactions cause the formation of a layered structure of Ti/Ti–Ga/Ti–As/GaAs. The depth distribution of electron concentration moves toward the Ti/GaAs interface as the annealing temperature increases. This is due to the growth of Ti–As, followed by the reduction of the channel thickness. The activation energy for the growth of Ti–As is determined to be 1.74 eV. The electron concentration in the channel layer decreases with the increase of the annealing temperature. This is due to the out-diffusion of Ga to the Ti film, resulting in the production of acceptor-type Ga vacancies and thereby the decrease of electron concentration in the channel. The activation energy for the reduction of electron concentration, equal to the formation energy of the acceptor-type Ga vacancies, is determined to be 1.42 eV. This is closed to the activation energy of 1.3 eV for the device failure obtained at annealing temperatures ranged from 300 to 350 °C. From these observations, it is proposed that the thermal degradation of GaAs MESFETs at temperatures 〈350 °C, mainly proceeds by the electron compensation with acceptor-type Ga vacancies in the channel, whereas it occurs by the growth of Ti–As below the original Ti/GaAs interface at temperatures 〉350 °C. © 1997 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 84 (1998), S. 911-917 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Microstructural reactions of Pd/Ge/Ti/Au contact to AlGaAs/InGaAs pseudomorphic high electron mobility transistor with an undoped GaAs/AlGaAs cap layer have been investigated using cross-sectional transmission electron microscopy, and the results are used to interpret the electrical properties of the ohmic contact. In the as-deposited state, a quaternary phase of PdxAlGaAs containing excess Ge atoms is formed at the interface of Pd/AlGaAs and some microvoids exist at the Pd layer in the vicinity of the interface. When the ohmic metals deposited on the undoped cap layer were annealed, the lowest contact resistivity of 9.1×10−5 Ω cm2 is obtained at 380 °C. AuGa compound is formed at the PdGe/undoped-AlGaAs interface as a result of the reaction between the ohmic metal and the undoped GaAs cap. This is due to the fast in-diffusion of Au toward the undoped AlGaAs through grain boundaries of the PdGe compound. The layer structure is changed to TiO/AuGa/PdGe/AuGa(TiAs+epi-Ge)/undoped-AlGaAs. The AuGa compound enhances the creation of group III vacancies, and the in-diffused Ge atoms occupy the vacancies. Thus, a number of electrons are produced below the contact, which plays a role in reducing the contact resistivity. For the ohmic metals deposited on n-AlGaAs by removing the undoped cap layer, the annealing temperature at which the contact resistivity has the minimum value of 2.3×10−6 Ω cm2 increases to 460 °C. The Au2Al is additionally observed at the PdGe/n-AlGaAs interface. Consequently, the layer structure is changed to TiO/AuGa/PdGe/AuGa+Au2Al(TiAs+epi-Ge)/n-type AlGaAs. The formation of Au2Al at the PdGe/n-AlGaAs interface creates more group III vacancies. Thus, the contact resistivity is further reduced by the incorporation of the in-diffused Ge into the group III vacancies. The InGaAs channel layer is observed to be intermixed in the annealed sample. This evidences the production of a large number of the group III vacancies via electrons below the contact. © 1998 American Institute of Physics.
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  • 4
    Electronic Resource
    Electronic Resource
    Woodbury, NY : American Institute of Physics (AIP)
    Applied Physics Letters 74 (1999), S. 2289-2291 
    ISSN: 1077-3118
    Source: AIP Digital Archive
    Topics: Physics
    Notes: The change of the Fermi energy level at the interface of Pd/p-type GaN by surface treatment was investigated using positron annihilation spectroscopy, and the results were used to provide interpretation of the electrical properties of the contact. Changes in the positron parameters at the interface in the aqua regia-treated GaN are more pronounced than that in the HCl-treated one. This provides evidence that the surface treatment with aqua regia prior to Pd metal deposition removes surface oxides, resulting in the shift of the Fermi level position from a middle of the bandgap to near the valence band. Thus, the barrier for hole injection from metal to p-type GaN is lowered, subsequent to the decrease of contact resistivity by two orders of magnitude. © 1999 American Institute of Physics.
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  • 5
    Electronic Resource
    Electronic Resource
    Woodbury, NY : American Institute of Physics (AIP)
    Applied Physics Letters 73 (1998), S. 2953-2955 
    ISSN: 1077-3118
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Ohmic contact to p-type GaN with the lowest contact resistivity was developed by the surface treatment prior to Pd/Au metal deposition. The contact resistivity drastically decreased from 2.9×10−2 to 4.3×10−4 Ω cm2 by the surface treatment using aqua regia. The surface treatment plays a role in removing the surface oxide formed on p-type GaN during epitaxial growth, and subsequently in reducing the barrier height for holes at the interface of Pd/p-type GaN, resulting in the good ohmic contacts to p-type GaN. © 1998 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    Woodbury, NY : American Institute of Physics (AIP)
    Applied Physics Letters 73 (1998), S. 1670-1672 
    ISSN: 1077-3118
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Microstructural evidence on direct contact of Au/Ge/Ni/Au ohmic metals to a InGaAs channel in AlGaAs/InGaAs pseudomorphic high electron mobility transistor with an undoped GaAs/AlGaAs cap layer was found using transmission electron microscopy, and the results were used to interpret the electrical properties of the contact. The lowest contact resistivity of 3.8×10−6 Ω cm2, obtained at 420 °C annealing, is due to the penetration of the interfacial compounds, Au2Ga and Au2Al, into the buried InGaAs channel. The direct contact of the compounds to the channel causes the reduction of series resistances between the ohmic compounds and the channel, resulting in the low contact resistivity. © 1998 American Institute of Physics.
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  • 7
    Electronic Resource
    Electronic Resource
    Woodbury, NY : American Institute of Physics (AIP)
    Applied Physics Letters 74 (1999), S. 2866-2868 
    ISSN: 1077-3118
    Source: AIP Digital Archive
    Topics: Physics
    Notes: A self-aligned gate pseudomorphic high-electron-mobility transistor (PHEMT) was developed through nonalloyed PdGe ohmic contact on an n+-GaAs cap layer. The lowest contact resistivity obtained was 1.2×10−7 Ω cm2 at 300 °C. This allows us to change the sequence on the formation of source/drain and gate electrodes in the process of PHEMT fabrication, namely self-aligned gate PHEMT. Performance of the self-aligned gate PHEMT was remarkably pronounced with annealing temperature or the decrease of contact resistivity. This is due to the solid-phase regrowth of highly Ge-doped GaAs below the PdGe contact, which acts to reduce barrier height for electron tunneling. © 1999 American Institute of Physics.
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  • 8
    Electronic Resource
    Electronic Resource
    Woodbury, NY : American Institute of Physics (AIP)
    Applied Physics Letters 71 (1997), S. 2656-2658 
    ISSN: 1077-3118
    Source: AIP Digital Archive
    Topics: Physics
    Notes: The Pd/Ge/Ti/Au ohmic contact to AlGaAs/InGaAs pseudomorphic high electron mobility transistor was investigated with the etch depth of an undoped GaAs/AlGaAs cap layer. The contact resistivity decreases from 9.5×10−5 to 2.3×10−6 Ω cm2 when the contacts were formed on a n-Al0.23Ga0.77As layer by removing the undoped cap layer. X-ray diffraction results show that the good ohmic contact is due to the formation of Au2Al as well as β-AuGa. Both compounds play a role to create group-III vacancies, followed by the incorporation of Ge into group-III vacancies, namely, creation of free electron below the contact. This results in the considerable elimination of contact resistivity by lowering the effective tunneling barrier. © 1997 American Institute of Physics.
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  • 9
    Electronic Resource
    Electronic Resource
    Woodbury, NY : American Institute of Physics (AIP)
    Applied Physics Letters 73 (1998), S. 3247-3249 
    ISSN: 1077-3118
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Microstructural evidence on the formation of a heavily Ge-doped layer below Pd/Ge-based ohmic contact to AlGaAs/InGaAs pseudomorphic high electron mobility transistor was obtained. The contact resistivity is decreased by two orders of magnitude as InGaAs channel is intermixed. This originates from the formation of Au2Al and Au7Ga2 compounds below the contacts during annealing, via production of group III vacancies. The vacancies play a role in producing free electrons by the incorporation of Ge atoms, resulting in intermixing of InGaAs as well as reduction of contact resistivity. © 1998 American Institute of Physics.
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  • 10
    Electronic Resource
    Electronic Resource
    Woodbury, NY : American Institute of Physics (AIP)
    Applied Physics Letters 75 (1999), S. 1580-1582 
    ISSN: 1077-3118
    Source: AIP Digital Archive
    Topics: Physics
    Notes: The effects of deep levels on the transconductance dispersion in an AlGaAs/InGaAs pseudomorphic high electron mobility transistor was interpreted using capacitance deep level transient spectroscopy (DLTS). Transconductance was decreased by 10% in the frequency range of 10 Hz–10 kHz at the negative gate bias, but it was increased at the positive one. In the DLTS spectra, two hole trap-like signals corresponding to surface states were only observed at the negative pulse bias, whereas the DX-center with the activation energy of 0.42±0.01 eV were observed at the positive one. The activation energy agrees well with that obtained from the temperature dependence of the positive transconductance dispersion, 0.39±0.03 eV. These provide evidence that the positive and negative transconductance dispersions are due to the DX center and surface states, respectively. © 1999 American Institute of Physics.
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