ISSN:
0749-1581
Keywords:
Mercury-199 NMR
;
Solid-state NMR
;
CP/MAS
;
Hexakis(dimethyl sulphoxide)mercury(II) trifluoromethanesulphonate
;
Chemistry
;
Analytical Chemistry and Spectroscopy
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Hexakis(dimethyl sulphoxide)mercury(II) trifluoromethanesulphonate, [Hg(dmso)6](O3SCF3)2, is a stable, readily synthesized compound which is an excellent standard for setting up CP/MAS experiments in solid-state 199Hg NMR. The isotropic chemical shift, δISO -2313 ppm, is to lower frequency than that measured for the same material in solution. The static spectrum exhibits of powder pattern indicative of axial symmetry about the mercury atom, with a chemical shift anisotropy of 122 ppm.
Additional Material:
2 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/mrc.1260330113
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