In:
Journal of Applied Physics, AIP Publishing, Vol. 85, No. 4 ( 1999-02-15), p. 2408-2413
Abstract:
The structural phase diagrams of complex perovskites have been studied within the mean-field approximation. Various phase diagrams with possible topological structures of the 1/2{111}-, 1/2{110}-, and 1/2{100}-type ordered structures are obtained. The 1/2{111}- and 1/2{100}-type ordered structures have similar phase diagrams and their ordering transitions are both of the second kind, while the 1/2{110}-type ordered structure has a more complex phase diagram and its ordering transition is of the first kind. In the two-phase region of the phase diagram, the ordered phase’s composition deviates from that of the chemical formula towards the completely ordering composition which is 0.5 for the 1/2{111}-, 1/2{100}-type ordered structures and 0.25, 0.50, 0.75 for the 1/2{110}-type ordered structures.
Type of Medium:
Online Resource
ISSN:
0021-8979
,
1089-7550
Language:
English
Publisher:
AIP Publishing
Publication Date:
1999
detail.hit.zdb_id:
220641-9
detail.hit.zdb_id:
3112-4
detail.hit.zdb_id:
1476463-5
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