In:
Acta Physica Sinica, Acta Physica Sinica, Chinese Physical Society and Institute of Physics, Chinese Academy of Sciences, Vol. 48, No. 3 ( 1999), p. 446-
Abstract:
In this paper,(2+1) resonance-enhanced multiphoton ionization(REMPI) spectra of CF radical between 260—360nm have been investigated- CF radicals were produced by a pulsed dc discharge in the mixtures of Ar/CF4,Ar/CF2Cl2 or Ar/CF3COOH-A new vibrational progression of 5p Rydberg state with band origin of 67746cm-1 were observed between 260—305nm-The vibrational frequency ω′=1848cm-1,inharmonic constant ωe χe′=18-5cm-1 and the quantum defect δ=0-625 have been determined by the assigned REMPI spectra- Furthermore,the (2+1)REMPI spectra of CF radical between 310—360nm,were also observed and assigned as 3p(v′=2—6) resonant excitation- The related spectroscopic constants have been derived-
Type of Medium:
Online Resource
ISSN:
1000-3290
,
1000-3290
Language:
Unknown
Publisher:
Acta Physica Sinica, Chinese Physical Society and Institute of Physics, Chinese Academy of Sciences
Publication Date:
1999
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