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  • 1
    In: Journal of Geophysical Research: Atmospheres, American Geophysical Union (AGU), Vol. 104, No. D21 ( 1999-11-20), p. 26373-26399
    Abstract: We present the results of two independent analyses of trends in the vertical distribution of ozone. For most of the ozonesonde stations we use data that were recently reevaluated and reprocessed to improve their quality and internal consistency. The two analyses give similar results for trends in ozone. We attribute differences in results primarily to differences in data selection criteria, rather than in statistical trend models. We find significant decreases in stratospheric ozone at all stations in middle and high latitudes of the Northern Hemisphere from 1970 to 1996, with the largest decreases located between 12 and 21 km, and trends of −3 to −10%/decade near 17 km. The decreases are largest at the Canadian and the most northerly Japanese station and are smallest at the European stations and at Wallops Island. The mean midlatitude trend is largest, −7%/decade, from 12 to 18 km for 1970–1996, and the decrease in ozone is significant from 10.5 to 25 km. For 1980–1996, the decrease is more negative by 1–2%/decade, with a maximum trend of −9%/decade in the lowermost stratosphere. The trends vary seasonally from about 10 to 17 km, with largest ozone decreases in winter and spring. Trends in tropospheric ozone are highly variable and depend on the region. There are decreases or zero trends at the Canadian stations for 1970–1996, and decreases of −2 to −8%/decade for the mid‐troposphere for 1980–1996; the three European stations show increases for 1970–1996, but trends are close to zero for two stations for 1980–1996 and positive for one; there are increases in ozone for the three Japanese stations for 1970–1996, but trends are either positive or zero for 1980–1996. The United States stations show zero or slightly negative trends in tropospheric ozone after 1980. It is not possible to define reliably a mean tropospheric ozone trend for northern midlatitudes, given the small number of stations and the large variability in trends. The integrated column trends derived from the sonde data are consistent with trends derived from both surface‐based and satellite measurements of the ozone column.
    Type of Medium: Online Resource
    ISSN: 0148-0227
    Language: English
    Publisher: American Geophysical Union (AGU)
    Publication Date: 1999
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  • 2
    Online Resource
    Online Resource
    American Geophysical Union (AGU) ; 1998
    In:  Geophysical Research Letters Vol. 25, No. 2 ( 1998-01-15), p. 139-142
    In: Geophysical Research Letters, American Geophysical Union (AGU), Vol. 25, No. 2 ( 1998-01-15), p. 139-142
    Type of Medium: Online Resource
    ISSN: 0094-8276
    Language: English
    Publisher: American Geophysical Union (AGU)
    Publication Date: 1998
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  • 3
    In: Geophysical Research Letters, American Geophysical Union (AGU), Vol. 23, No. 12 ( 1996-06-01), p. 1533-1536
    Type of Medium: Online Resource
    ISSN: 0094-8276
    Language: English
    Publisher: American Geophysical Union (AGU)
    Publication Date: 1996
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  • 4
    Online Resource
    Online Resource
    American Geophysical Union (AGU) ; 1996
    In:  Journal of Geophysical Research: Atmospheres Vol. 101, No. D22 ( 1996-12-20), p. 29179-29200
    In: Journal of Geophysical Research: Atmospheres, American Geophysical Union (AGU), Vol. 101, No. D22 ( 1996-12-20), p. 29179-29200
    Abstract: Ozone profiles obtained by near‐daily ozonesonde observations during campaigns at several sites in the North Atlantic are used to construct time‐height cross sections of ozone concentration through the troposphere. Strong day‐to‐day ozone variability on the scale of synoptic meteorological disturbances is found both in the spring and in the summer throughout much of the troposphere. Layers of high ozone concentration (∼100 ppb) are frequently seen in the middle and upper troposphere and are invariably associated with transport characteristics that strongly support a stratospheric source for these layers. Regions of low ozone ( 〈 40 ppb) are seen in the middle and upper troposphere associated with higher relative humidity. The connection of these events with low surface mixing ratios suggests that convective processes mix air low in ozone up through the troposphere. Vertical layering of ozone mixing ratio, which is seen at all of the observing locations, is a result of differing sources of air in the different layers.
    Type of Medium: Online Resource
    ISSN: 0148-0227
    Language: English
    Publisher: American Geophysical Union (AGU)
    Publication Date: 1996
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  • 5
    Online Resource
    Online Resource
    American Geophysical Union (AGU) ; 1996
    In:  Geophysical Research Letters Vol. 23, No. 3 ( 1996-02-01), p. 293-296
    In: Geophysical Research Letters, American Geophysical Union (AGU), Vol. 23, No. 3 ( 1996-02-01), p. 293-296
    Type of Medium: Online Resource
    ISSN: 0094-8276
    Language: English
    Publisher: American Geophysical Union (AGU)
    Publication Date: 1996
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  • 6
    Online Resource
    Online Resource
    American Geophysical Union (AGU) ; 1996
    In:  Journal of Geophysical Research: Atmospheres Vol. 101, No. D6 ( 1996-04-30), p. 10017-10060
    In: Journal of Geophysical Research: Atmospheres, American Geophysical Union (AGU), Vol. 101, No. D6 ( 1996-04-30), p. 10017-10060
    Abstract: This paper describes the validation of ozone data from the Upper Atmosphere Research Satellite (UARS) Microwave Limb Sounder (MLS). The MLS ozone retrievals are obtained from the calibrated microwave radiances (emission spectra) in two separate bands, at frequencies near 205 and 183 GHz. Analyses described here focus on the MLS Version 3 data (the first set of files made publicly available). We describe results of simulations performed to assess the quality of the retrieval algorithms, in terms of both mixing ratio and radiance closure. From actual MLS observations, the 205‐GHz ozone retrievals give better closure (smaller radiance residuals) than that from the 183‐GHz measurements and should be considered more accurate from the calibration aspects. However, the 183‐GHz data are less noise limited in the mesosphere and can provide the most useful scientific results in that region. We compare the retrieved 205‐GHz ozone profiles in the middle‐to lower stratosphere to ozonesonde measurements at a wide range of latitudes and seasons. Ground‐based lidar data from Table Mountain, California, provide a good reference for comparisons at higher altitudes. Based on these analyses, comparisons with balloon‐borne measurements and others, as well as a detailed budget of estimated uncertainties, MLS results appear to be generally of high quality, with some biases worth mentioning. Results for the lowermost stratosphere (∼50 to 100 hPa) are still in need of improvement. A set of estimated precision and accuracy values is derived for the MLS ozone data sets. We also comment on recent updates in the retrieval algorithms and their impact on ozone values.
    Type of Medium: Online Resource
    ISSN: 0148-0227
    Language: English
    Publisher: American Geophysical Union (AGU)
    Publication Date: 1996
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  • 7
    Online Resource
    Online Resource
    Wiley ; 1997
    In:  Quarterly Journal of the Royal Meteorological Society Vol. 123, No. 543 ( 1997-10), p. 2009-2040
    In: Quarterly Journal of the Royal Meteorological Society, Wiley, Vol. 123, No. 543 ( 1997-10), p. 2009-2040
    Type of Medium: Online Resource
    ISSN: 0035-9009 , 1477-870X
    URL: Issue
    RVK:
    RVK:
    Language: English
    Publisher: Wiley
    Publication Date: 1997
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  • 8
    Online Resource
    Online Resource
    American Geophysical Union (AGU) ; 1996
    In:  Journal of Geophysical Research: Atmospheres Vol. 101, No. D22 ( 1996-12-20), p. 29213-29227
    In: Journal of Geophysical Research: Atmospheres, American Geophysical Union (AGU), Vol. 101, No. D22 ( 1996-12-20), p. 29213-29227
    Abstract: A large‐scale view of O 3 transport over the western North Atlantic Ocean (WNAO) in summer illustrates distinct sources of O 3 , and separate transport mechanisms are important at different vertical levels in the troposphere. The week‐long period presented covers a sequence of O 3 sondes released from Bermuda and encompasses two surface O 3 events in the month‐long NARE intensive. O 3 and CO peaked at Chebogue Point on the evening of August 25 and after midnight on the morning of August 28. At Sable Island, peaks occurred during early morning of August 26 and late morning of August 28. These events occurred under W‐SW winds associated with advancing low‐pressure systems that transported anthropogenic pollutants over the WNAO. The concentrations dropped with the passage of a trough or a cold front. Evidence suggests the surface was occasionally isolated from polluted air during favorable transport with pollutants lifted in warm sector flow riding over a wedge of cool, thermodynamically stable air. In addition to surface O 3 , the O 3 ‐sonde profile over Bermuda on the morning of August 27 showed a deep layer of O 3 from 6 to 12 km. Using back trajectories and two tracers (isentropic potential vorticity and water vapor), we illustrate that stratospheric ozone exchanged into the upper troposphere in conjunction with surface cyclogenesis was advected through the middle to upper troposphere over the midlatitudes with the potential to reach lower altitudes through subsidence in regions of anticyclonic motion.
    Type of Medium: Online Resource
    ISSN: 0148-0227
    Language: English
    Publisher: American Geophysical Union (AGU)
    Publication Date: 1996
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  • 9
    In: Journal of Geophysical Research: Atmospheres, American Geophysical Union (AGU), Vol. 101, No. D6 ( 1996-04-30), p. 10129-10149
    Abstract: The Upper Atmosphere Research Satellite (UARS) microwave limb sounder (MLS) makes measurements of thermal emission at 183.3 GHz which are used to infer the concentration of water vapor over a pressure range of 46 – 0.2 hPa (∼20 to ∼60 km). We provide a validation of MLS H 2 O by analyzing the integrity of the measurements, by providing an error characterization, and by comparison with data from other instruments. It is estimated that version 3 MLS H 2 O retrievals are accurate to within 20–25% in the lower stratosphere and to within 8–13 % in the upper stratosphere and lower mesosphere. The precision of a single profile is estimated to be ∼0.15 parts per million by volume (ppmv) in the midstratosphere and 0.2 ppmv in the lower and upper stratosphere. In the lower mesosphere the estimate of a single profile precision is 0.25–0.45 ppmv. During polar winter conditions, H 2 O retrievals at 46 hPa can have a substantial contribution from climatology. The vertical resolution of MLS H 2 O retrievals is ∼5 km.
    Type of Medium: Online Resource
    ISSN: 0148-0227
    Language: English
    Publisher: American Geophysical Union (AGU)
    Publication Date: 1996
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  • 10
    Online Resource
    Online Resource
    American Geophysical Union (AGU) ; 1995
    In:  Geophysical Research Letters Vol. 22, No. 18 ( 1995-09-15), p. 2493-2496
    In: Geophysical Research Letters, American Geophysical Union (AGU), Vol. 22, No. 18 ( 1995-09-15), p. 2493-2496
    Type of Medium: Online Resource
    ISSN: 0094-8276
    Language: English
    Publisher: American Geophysical Union (AGU)
    Publication Date: 1995
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