In:
Journal of Materials Research, Springer Science and Business Media LLC, Vol. 13, No. 3 ( 1998-03), p. 754-759
Abstract:
Mixed crystalline tin-titanium phosphates with variable tin-to-titanium molar ratio have been prepared by precipitation of soluble salts of the metal (IV) with phosphoric acid and refluxing the amorphous solids in 17 M H 3 PO 4 . The new materials are characterized by chemical textural and thermal analysis and x-ray powder diffraction. The tin-titanium phosphates are solid solutions showing an isomorphic substitution of tin by titanium in the α-tin phosphate lattice and tin substitution in the γ-titanium phosphate lattice. In both cases, the solubility is partial. The coexistence of both saturated phases is observed in samples of composition between the solubility limits.
Type of Medium:
Online Resource
ISSN:
0884-2914
,
2044-5326
DOI:
10.1557/JMR.1998.0095
Language:
English
Publisher:
Springer Science and Business Media LLC
Publication Date:
1998
detail.hit.zdb_id:
54876-5
detail.hit.zdb_id:
2015297-8
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