Electronic Resource
College Park, Md.
:
American Institute of Physics (AIP)
The Journal of Chemical Physics
113 (2000), S. 2741-2759
ISSN:
1089-7690
Source:
AIP Digital Archive
Topics:
Physics
,
Chemistry and Pharmacology
Notes:
We investigate spectral properties of random manifolds, which consist of a bright state coupled to mutually uncoupled dark states for an equal but otherwise arbitrary distribution of the couplings. Both Poisson and Wigner distributions of the energy spacings of the dark states are taken into account. The Poisson spacing model is solved exactly. The average spectrum is Lorentzian. The average dilution factor comes out to be a function alone of the mean coupling strength normalized to the mean neighbor spacing of the dark states. A simple expression for the explored fraction of the available phase space is obtained. Numerical studies indicate that the normalized coupling even controls the whole distribution of the dilution factor for the Poisson model. For weak mean coupling strength a secondary peak occurs in this distribution for both the Poisson and the Wigner model. A perturbational analysis shows that this peak leads back to accidental resonances of the bright state with single dark states. A simple tier model is suggested for treating the intermixing of vibrational dark basis states in molecules. Results are compared with experimental data. © 2000 American Institute of Physics.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1063/1.1305526
Permalink
|
Location |
Call Number |
Limitation |
Availability |
