In:
CHIMIA, Swiss Chemical Society, Vol. 55, No. 11 ( 2001-11-28), p. 972-
Abstract:
The natural resin mastic, composed largely of triterpenes, is used as a varnish on artwork. This study investigates the influence of light on the autoxidation and yellowing of mastic, both during harvest and after application as a film. The nature of photoinitiation reactions is considered,
as is the propagation of oxidative processes in both light and darkness. Oxidation, radical content and yellowing were studied by graphite-assisted laser desorption mass spectrometry, EPR and UV/VIS spectrometry, respectively. Exposure to sunlight during harvesting is found to strongly affect the resin. The radical content increases dramatically, and oxidation is accelerated. These differences are also observed during artificial aging under a range of conditions. Mastic that is harvested without exposure to sunlight deteriorates less quickly in all respects. This is attributed
to lack of sunlight-generated radicals and/or labile radical precursors, which are very long-lived in the viscous resin or solid film. Remarkably, radicals are found to be nearly as prevalent in dark-aged films as those aged in light. Oxidation in the dark is also nearly as fast as with continuous light exposure. These results suggest that dark and light aging are not fundamentally different, in contrast to the conventional model.
Type of Medium:
Online Resource
ISSN:
2673-2424
,
0009-4293
DOI:
10.2533/chimia.2001.972
Language:
Unknown
Publisher:
Swiss Chemical Society
Publication Date:
2001
detail.hit.zdb_id:
2179192-2
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