In:
Journal of Chemical Research, SAGE Publications, Vol. 2003, No. 5 ( 2003-05), p. 307-309
Abstract:
Two novel copper complexes with formulae [Cu{HC(pz) 3 }(SCN) 2 ] 1 and [Cu(tacn)(SCN) 2 ] 2 have been obtained by the reaction of HC(pz) 3 and tacn with a copper salt and thiocyanate. The complex 1 crystallises in the orthorhombic space group A ba2 , with lattice parameters a = 25.7715(7) Å, b = 7.5034(3) Å, c = 16.2328(6) Å, Z = 8, R 1 = 0.0613, wR 2 = 0.1353. The complex 2 crystallises in the orthorhombic space group P 2(1)2(1)2(1) , with lattice parameters a = 8.640(4) Å, b = 10.890(5) Å, c = 13.833(6) Å, Z = 4, R 1 = 0.0343, wR 2 = 0.0679. Both complexes are isostructural mononuclear compounds. The central copper ions of 1 and 2 are coordinated by three nitrogen atoms of the ligands and two nitrogen atoms of the two thiocyanate ions. Depending on the ligands, the two complexes forms different weak bonds resulting in different crystal packing.
Type of Medium:
Online Resource
ISSN:
1747-5198
,
2047-6507
DOI:
10.3184/030823403103173921
Language:
English
Publisher:
SAGE Publications
Publication Date:
2003
detail.hit.zdb_id:
3010810-X
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