In:
European Journal of Inorganic Chemistry, Wiley, Vol. 2004, No. 24 ( 2004-12), p. 4789-4794
Abstract:
Manganese(II) complexes with the ligand 9′‐[4,5‐bis(methylthio)‐1,3‐dithiol‐2‐ylidene]‐4′,5′‐diazafluorene (L) have been synthesized, and the single‐crystal structures of complexes [Mn(L) 2 (H 2 O) 2 ](ClO 4 ) 2 ·(L) 2 ·2C 2 H 5 OH·2CH 3 CN ( 1 ), [Mn(L) 2 Cl 2 ]·1.5CH 2 Cl 2 ( 2 ) and [Mn(L) 2 (NO 3 ) 2 ] ( 3 ) have been characterized. Complex 1 is trans ‐coordinated with N ··· H−O and S ··· S contacts, while the other two complexes are cis ‐coordinated with short π ··· π stacking. Solvent‐free powder samples were also obtained and these complexes showed catalytic activity in the decomposition of H 2 O 2 in the presence of added imidazole; the perchlorate compound was the most effective. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2004)
Type of Medium:
Online Resource
ISSN:
1434-1948
,
1099-0682
DOI:
10.1002/ejic.v2004:24
DOI:
10.1002/ejic.200400330
Language:
English
Publisher:
Wiley
Publication Date:
2004
detail.hit.zdb_id:
1475009-0
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