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  • 2000-2004  (2)
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  • 2000-2004  (2)
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  • 1
    Online Resource
    Online Resource
    Oxford University Press (OUP) ; 2001
    In:  Bulletin of the Chemical Society of Japan Vol. 74, No. 9 ( 2001-09-01), p. 1737-1742
    In: Bulletin of the Chemical Society of Japan, Oxford University Press (OUP), Vol. 74, No. 9 ( 2001-09-01), p. 1737-1742
    Abstract: A ferrocenyl end-substituted terthiophenes derivative and a sexithiophene derivative were prepared as model compounds for a molecular wire. Electrochemical measurements and absorption spectroscopy were performed to elucidate the oxidation process and the oxidized states of those model compounds. The first oxidation of the model compounds took place in the ferrocene moieties (terminals). The resultant oxidized species in the ferrocene moieties seeped into the oligothiophene moieties (wires) and spread over two or three thiophene rings. Further oxidation of the ferrocenyl-terthiophene derivative did not occur, whereas that of the ferrocenyl-sexithiophene derivative produced an oxidized species, such as a cation radical in the sexithiophene moiety.
    Type of Medium: Online Resource
    ISSN: 0009-2673 , 1348-0634
    RVK:
    Language: English
    Publisher: Oxford University Press (OUP)
    Publication Date: 2001
    detail.hit.zdb_id: 2041163-7
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  • 2
    Online Resource
    Online Resource
    IOP Publishing ; 2000
    In:  Japanese Journal of Applied Physics Vol. 39, No. 9A ( 2000-09-01), p. L939-
    In: Japanese Journal of Applied Physics, IOP Publishing, Vol. 39, No. 9A ( 2000-09-01), p. L939-
    Abstract: Methoxyterthiophene substituted with two terminal ferrocenyl groups was prepared. The oxidation process and the oxidized state of the compound were investigated by cyclic voltammetry, coulometry, and electronic absorption spectroscopy. The measurements show that an oxidized species is first produced on a ferrocene moiety and definitely interacts not only with the methoxythiophene moiety but also with the other ferrocene moiety. This indicates that the oxidized species spread over almost the entire molecule.
    Type of Medium: Online Resource
    ISSN: 0021-4922 , 1347-4065
    RVK:
    RVK:
    RVK:
    Language: Unknown
    Publisher: IOP Publishing
    Publication Date: 2000
    detail.hit.zdb_id: 218223-3
    detail.hit.zdb_id: 797294-5
    detail.hit.zdb_id: 2006801-3
    detail.hit.zdb_id: 797295-7
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