In:
European Journal of Inorganic Chemistry, Wiley, Vol. 2004, No. 8 ( 2004-04), p. 1701-1704
Abstract:
A new trisulfoxide ligand, 1,3,5‐tris(ethylsulfinyl)‐2,4,6‐trimethylbenzene (L), was designed and synthesized, and treated with Ln(NO 3 ) 3 or Ln(ClO 4 ) 3 to produce three coordination polymers: [Ln(L)(MeOH)(NO 3 ) 3 ] n [where Ln = La III ( 1 ); Nd III ( 2 )] and {[La(L)(DMF) 5 ](ClO 4 ) 3 } n ( 3 ). Solid‐state structures of all three complexes were determined by single‐crystal X‐ray diffraction. The three complexes have 1D helical‐chain structures and complexes 1 and 2 are isostructural. To the best of our knowledge, these coordination polymers are the first examples of (trisulfoxide)metal complexes. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2004)
Type of Medium:
Online Resource
ISSN:
1434-1948
,
1099-0682
DOI:
10.1002/ejic.v2004:8
DOI:
10.1002/ejic.200300751
Language:
English
Publisher:
Wiley
Publication Date:
2004
detail.hit.zdb_id:
1475009-0
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