In:
Zeitschrift für Naturforschung A, Walter de Gruyter GmbH, Vol. 57, No. 6-7 ( 2002-7-1), p. 581-585
Kurzfassung:
155 Gd Mössbauer spectroscopic studies of the title complexes have been performed. Although the 155Gd isomer shifts (d) varied scarcely, the quadrupole coupling constants (e 2 qQ) changed in the range 4.07-4.81 mm s-1. The e 2 qQ values of KGdM(CN) 6 · 3H 2 O (M = Fe II and Ru II ) are larger than those of GdM(CN) 6 · 4H 2 O (M = Cr III , Fe III , and Co III ), these values increasing with increasing orthorhombic distortion of the crystal structures. A relationship between the e 2 qQ values and the ionic radii of the transition metal ions has also been recognized
Materialart:
Online-Ressource
ISSN:
1865-7109
,
0932-0784
DOI:
10.1515/zna-2002-6-752
Sprache:
Englisch
Verlag:
Walter de Gruyter GmbH
Publikationsdatum:
2002
ZDB Id:
2079610-9
ZDB Id:
124634-3
ZDB Id:
124633-1
ZDB Id:
2767412-5
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