In:
Canadian Journal of Chemistry, Canadian Science Publishing, Vol. 82, No. 5 ( 2004-05-01), p. 616-621
Abstract:
A novel organic-templated zincophosphate, namely (C 6 H 16 N 2 )[Zn(HPO 4 ) 2 ], was hydrothermally synthesized and X-ray single-crystal structural analysis reveals that the anions [Zn(HPO 4 ) 2 ] 2 , which have square-twisted chains containing corner-sharing four-rings of alternating ZnO 4 and PO 4 tetrahedra, are assemblied via self-complementary strong and symmetrical hydrogen-bonding R 2 2 (8) synthons between the phosphate groups into three-dimensional hydrogen bond frameworks featuring three-dimensional intersecting pseudochannels. The doubly protonated 2,5-dimethylpiperazinium cations are attached to the three-dimensional inorganic framework via N-H···O hydrogen bonds to strengthen the 3-D network.
Type of Medium:
Online Resource
ISSN:
0008-4042
,
1480-3291
Language:
English
Publisher:
Canadian Science Publishing
Publication Date:
2004
detail.hit.zdb_id:
1482256-8
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