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  • 11
    ISSN: 0009-286X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Wear of automatic pump valves by abrasive suspensions. In pumping of abrasive suspensions with reciprocating displacement pumps against high pressures, the pump valves prove to be subject to serious wear. Wear of the piston seal can usually be avoided by washing or by separating membranes. Pump valves are fitted with elastic or rigid seals. To resist corrosion and temperature effects, frequently the only possible approach is to finish them in metallic or carbide materials. The major kinds of wear are demonstrated by a tribological study. The rates of wear found for a real valve model with a high pressure experimental setup depend upon the pressure and frequency of reciprocation. A hardness-dependent region of instability exists where wear scoring arises. The volume wear rate for various arrangements of materials and abrasive particles exhibits a crest/trough nature. A design strategy and construction aspects are considered and compared with practical experience.
    Additional Material: 22 Ill.
    Type of Medium: Electronic Resource
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  • 12
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Chemie Ingenieur Technik - CIT 61 (1989), S. 136-140 
    ISSN: 0009-286X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Accuracy of dosage. Confusion sometimes surrounds the concept of dosage accuracy. For this reason, standard definitions and testing and calculation procedures are proposed for dosage accuracy, dosage error, and dosage constancy. Representation of the relationship between dosage error and dosage constancy within the area of tolerance of the dosage accuracy is new. Since the measurement of all error quantities is always bound to relate terms such as short-term, long-term, and momentary dosage error to a stated time base. This also facilitates a conceptually smooth transition to operating dosage errors observed in long-term operation. It would be convenient if some standardization of the concepts, and possibly a set of rules, could be developed on this basis. Evaluation of measured results on comparing guarantees would then be conducted in relation to the accuracy of measurement.
    Additional Material: 13 Ill.
    Type of Medium: Electronic Resource
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  • 13
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Chemie Ingenieur Technik - CIT 58 (1986), S. 183-195 
    ISSN: 0009-286X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Pumps and compressors for high pressures - strength, seals, wear. In high pressure processes pumps and compressors are used for the pressure range of 100 to 4 000 bar. Very careful design is necessary because of the extreme mechanical demands. The special features of high pressure technology are explained. The methods used for generating high pressures - displacement or fluid flow machine - impose design limitations, partly by the final temperature, Mach number, material fatigue, or vibrations. A survey of typical high pressure pumps and compressors shows the range and limitations of application. There is a definite trend to leak-free systems. The best design of thick-walled components with pulsating pressureload avoids grooves, requires smooth surfaces, and uses tough, clean, and high-strength steels. The various designs of dynamic seals are explained and the state of the art is depicted. Detailed reference is also made to the exceptionally difficult wear problem of oscillating pump valves with abrasive suspensions.
    Additional Material: 26 Ill.
    Type of Medium: Electronic Resource
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  • 14
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Chemie Ingenieur Technik - CIT 57 (1985), S. 218-229 
    ISSN: 0009-286X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Leakfree oscillating positive-displacement pumps - state of the art and trends of development. Leak- and maintenance-free oscillating positive-displacement pumps are very important for avoiding pollution and improving the reliability of plants. Technical progress in the field of hydraulic diaphragm- and tube-pumps for high pressures are explained. The actual data (pressure, efficiency, temperature) and experience with different fluids are surveyed. The various hydraulic control systems, the diaphragm design, and methods for rupture-control are compared. Further development trends are explained.
    Additional Material: 20 Ill.
    Type of Medium: Electronic Resource
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  • 15
    ISSN: 0009-286X
    Keywords: Schneckendosierer ; Zulaufbedingungen ; Dosie strom-Schwankungen ; Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
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  • 16
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Chemie Ingenieur Technik - CIT 58 (1986), S. 442-443 
    ISSN: 0009-286X
    Keywords: Apparat ; Druckbehälter ; Zylinderschale ; Lagerung ; Abstützung ; Tragelement ; Tragpratze ; Zusatzkräfte ; lokale Belastungen ; Spannungen ; Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
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  • 17
    Electronic Resource
    Electronic Resource
    Chichester : Wiley-Blackwell
    Biological Mass Spectrometry 20 (1985), S. 266-267 
    ISSN: 0030-493X
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
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  • 18
    Electronic Resource
    Electronic Resource
    Chichester : Wiley-Blackwell
    Biological Mass Spectrometry 21 (1986), S. 85-89 
    ISSN: 0030-493X
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The electron impact mass spectra of the pyrrolidides of both the cis- and trans-octylcyclohexanecarboxylic acids show the structure of the aliphatic chain, despite the steric hindrance of a direct H transfer from the chain to the functional group.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
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  • 19
    Electronic Resource
    Electronic Resource
    Chichester : Wiley-Blackwell
    Biological Mass Spectrometry 23 (1988), S. 566-572 
    ISSN: 0030-493X
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Triazolopyridine is proposed as a new derivative for the location of branches and double bonds in fatty acids. It is compared with previously used derivatives and found to be clearly superior to the pyrrolidide and slightly superior to the β-picolinyl ester with regard to the structure-specific fragmentation pattern. It is prepared by reacting the activated acid with 2-hydrazinopyridine followed by cyclization.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
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  • 20
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 260 (1949), S. 242-248 
    ISSN: 0372-7874
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die Konzentration von NO2 in 7 n bis 14,5 n Salpetersäure wird aus der Abweichung des Potentials des Redoxsystems HNO2/HNO3 vom Logarithmus der analytischen HNO2- Konzentration im Temperaturbereich von 20° bis 100° C bestimmt. Hierbei kann auf Grund einer Abschätzung der Gleichgewichtskonstante K4 = [HNO2]/[N2O4] die Anwesenheit von N2O4 vernachlässigt werden.Log K zeigt eine lineare Abhängigkeit von 1/T. Die Reaktionswärmen werden aus dem Temperaturkoeffizienten ermittelt und die BUNSENschen Absorptionskoeffizienten von NO2 angenähert angegeben.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
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