In:
Acta Crystallographica Section B Structural Science, International Union of Crystallography (IUCr), Vol. 65, No. 6 ( 2009-12-01), p. 699-706
Abstract:
Reaction of silver(I) salts with three equivalents of tri- p -tolylphosphine in CH 3 CN resulted in a series of isomorphous complexes [Ag X {P(4-MeC 6 H 4 ) 3 } 3 ] ( X = Br, SCN, ClO 4 ). These complexes all crystallize in the orthorhombic space group Pna 2 1 . The complexes with X = Br, SCN are distorted tetrahedral around the silver(I) atom, whereas the ClO 4 − complex is distorted trigonal planar around the silver. The new complexes are compared with each other using r.m.s. overlay calculations as well as half-normal probability plot analysis and with the previously reported isomorphous chloride, bromide as well as the non-isomorphous iodide complexes.
Type of Medium:
Online Resource
ISSN:
0108-7681
DOI:
10.1107/S0108768109036404
DOI:
10.1107/S0108768109036404/ps5003sup1.cif
DOI:
10.1107/S0108768109036404/ps5003Isup2.fcf
DOI:
10.1107/S0108768109036404/ps5003IIsup3.fcf
DOI:
10.1107/S0108768109036404/ps5003IIIsup4.fcf
DOI:
10.1107/S0108768109036404/ps5003sup5.pdf
Language:
Unknown
Publisher:
International Union of Crystallography (IUCr)
Publication Date:
2009
detail.hit.zdb_id:
2020841-8
SSG:
13
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