In:
Zeitschrift für anorganische und allgemeine Chemie, Wiley, Vol. 635, No. 15 ( 2009-12), p. 2671-2675
Abstract:
Two coordination polymers, namely [Zn(L1)(OAc)]·H 2 O ( 1 ) and [Cd(L1) 2 ] ( 2 ), where L1 = 3,5‐bis(pyridin‐4‐ylmethoxy)benzoic acid, have been synthesized under hydrothermal conditions and characterized by single‐crystal X‐ray diffraction analysis. Complex 1 has a 2D layer structure in which the hydrogen bonds between lattice water molecules and uncoordinated carboxylate oxygen atoms of the ligand L1 in the adjacent layers extend the 2D layer into a 3D supramolecular architecture. The structure of 2 is a 2D (3,5)‐connected net with (3·5 2 )(3 2 ·5 3 ·6 4 ·7) topology. In addition, the luminescent properties of complexes 1 and 2 have been studied in the solid state at room temperature.
Type of Medium:
Online Resource
ISSN:
0044-2313
,
1521-3749
DOI:
10.1002/zaac.v635:15
DOI:
10.1002/zaac.200900170
Language:
English
Publisher:
Wiley
Publication Date:
2009
detail.hit.zdb_id:
201094-X
detail.hit.zdb_id:
1481139-X
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