In:
Zeitschrift für anorganische und allgemeine Chemie, Wiley, Vol. 635, No. 2 ( 2009-02), p. 361-364
Abstract:
A inorganic‐organic hybrid zinc phosphite (C 2 H 3 N 3 )Zn(HPO 3 ) ( 1 ) has been prepared under solvothermal conditions in the presence of 1,2,4‐triazole (trz) ligand.Its structure was determined by single‐crystal X‐ray diffraction, and further characterized by powder X‐ray diffraction (XRD), FTIR spectroscopy, elemental analysis, ICP analysis, thermogravimetric analysis and fluorescent spectrum. It crystallizes in the monoclinic system, space group P 2 1 / n , a = 7.5515(6) Å, b = 9.1813(8) Å, c = 10.0125(8) Å, β = 111.267(1)°, V = 646.92(9) Å 3 , Z = 4. The structure consists of left‐handed and right‐handed helical chains that are connected through bridging oxygen atoms to form a two‐dimensional layer structure with 4.8‐net. The compound exhibits intense photoluminescence upon photo‐excitation at 326 nm.
Type of Medium:
Online Resource
ISSN:
0044-2313
,
1521-3749
DOI:
10.1002/zaac.200800384
Language:
English
Publisher:
Wiley
Publication Date:
2009
detail.hit.zdb_id:
201094-X
detail.hit.zdb_id:
1481139-X
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