Description: With the warming climate, ice masses on Earth are expected to increasingly contribute to a rising sea level. As for any material, the ice bodies’ temperature is a key variable to change the material’s properties, especially the rheology. In the case of ice in natural environments on Earth, temperature is always close to the material’s melting point. Therefore ice can be regarded as a ‘hot material’ (homologous temperatures T/T_m ca. 0.7 to 0.9). This means that recrystallization plays a decisive role in governing the state and thus the behaviour of the material, as it continuously resets the mechanical properties. Recrystallization as a set of control mechanisms has been recognized and interpreted in many ice cores in the last decades, and certain recrystallization regimes have been assigned to special ice-sheet depth ranges. This assignment was based on microstructure observations (mainly grain size) and estimated boundary conditions (temperature and stress/strain amounts) which change systematically with depth. To generalize the use of recrystallization regimes we decouple their occurrence from the ice-sheet depth information and connect them directly to the activators and causes: strain rate and temperature.

Description: ABSTRACT. We investigated the large-scale (10–1000m) and small-scale (mm–cm) variations in size, number and arrangement of air bubbles in the EPICA Dronning Maud Land (EDML) (Antarctica) ice core, down to the end of the bubble/hydrate transition (BHT) zone. On the large scale, the bubble number density shows a general correlation with the palaeo-temperature proxy, d18O, and the dust concentration, which means that in Holocene ice there are fewer bubbles than in glacial ice. Small-scale variations in bubble number and size were identified and compared. Above the BHT zone there exists a strong anticorrelation between bubble number density and mean bubble size. In glacial ice, layers of high number density and small bubble size are linked with layers with high impurity content, identified as cloudy bands. Therefore, we regard impurities as a controlling factor for the formation and distribution of bubbles in glacial ice. The anticorrelation inverts in the middle of the BHT zone. In the lower part of the BHT zone, bubble-free layers exist that are also associated with cloudy bands. The high contrast in bubble number density in glacial ice, induced by the impurities, indicates a much more pronounced layering in glacial firn than in modern firn.

Description: An important feature of natural ice, in addition to the obvious relevance of glaciers and ice sheets for climate-related issues, is its ability to creep on geological time scales and low deviatoric stresses at temperatures very close to its melting point, without losing its polycrystalline character. This fact, together with its strong mechanical anisotropy and other notable properties, makes natural ice an interesting model material for studying the high-temperature creep and recrystallization of rocks in Earth’s interior. After having reviewed the major contributions of deep ice coring to the research on natural ice microstructures in Part I of this work (Faria et al., 2014), here in Part II we present an up-todate view of the modern understanding of natural ice microstructures and the deformation processes that may produce them. In particular, we analyze a large body of evidence that reveals fundamental flaws in the widely accepted tripartite paradigm of polar ice microstructure (also known as the “three-stage model,” cf. Part I). These results prove that grain growth in ice sheets is dynamic, in the sense that it occurs during deformation and is markedly affected by the stored strain energy, as well as by air inclusions and other impurities. The strong plastic anisotropy of the ice lattice gives rise to high internal stresses and concentrated strain heterogeneities in the polycrystal, which demand large amounts of strain accommodation. From the microstructural analyses of ice cores, we conclude that the formation of many and diverse subgrain boundaries and the splitting of grains by rotation recrystallization are the most fundamental mechanisms of dynamic recovery and strain accommodation in polar ice. Additionally, in fine-grained, high-impurity ice layers (e.g. cloudy bands), strain may sometimes be accommodated by diffusional flow (at low temperatures and stresses) or microscopic grain boundary sliding via microshear (in anisotropic ice sheared at high temperatures). Grain boundaries bulged by migration recrystallization and subgrain boundaries are endemic and very frequent at almost all depths in ice sheets. Evidence of nucleation of new grains is also observed at various depths, provided that the local concentration of strain energy is high enough (which is not seldom the case). As a substitute for the tripartite paradigm, we propose a novel dynamic recrystallization diagram in the three-dimensional state space of strain rate, temperature, and mean grain size, which summarizes the various competing recrystallization processes that contribute to the evolution of the polar ice microstructure. Dedicated to Sepp Kipfstuhl on occasion of his 60th birthday.

Description: Ice is the most frequent mineral on the Earth’s surface, however experiences conditions comparable to silicate minerals at high metamorphic grades. In all natural conditions ice is a hot material with homologous temperatures between 0.9 and 0.7 at least. Under such circumstances recrystallization plays a decisive role in governing the state and thus the behaviour of the material. This has been recognized and interpreted in many ice cores in the last decades (Faria et al. in press a) assigning recrystallization regimes to ice sheet depth ranges. This assignment made use of microstructure observations (mainly grain size) and estimated boundary conditions (temperature and stress/strain amounts) which change systematically with depth. To generalize the use of recrystallization regimes we decouple their occurrence from the ice sheet depth information and connect them directly to the activators and causes: strain rate and temperature (Faria et al. in press b). References: Faria, S. H.; Weikusat, I. & Azuma, N. The Microstructure of Polar Ice. Part I: Highlights from ice core research. Journal of Structural Geology , in press a, DOI: 10.1016/j.jsg.2013.09.010 Faria, S. H.; Weikusat, I. & Azuma, N. The Microstructure of Polar Ice. Part II: State of the Art. Journal of Structural Geology , in press b, DOI: 10.1016/j.jsg.2013.11.003

Description: Polar ice sheets play a fundamental role in Earth's climate system, by interacting actively and passively with the environment. Active interactions include the creeping flow of ice and its effects on polar geomorphology, global sea level, ocean and atmospheric circulation, and so on. Passive interactions are mainly established by the formation of climate records within the ice, in form of air bubbles, dust particles, salt microinclusions and other derivatives of airborne impurities buried by recurrent snowfalls. For a half-century scientists have been drilling deep ice cores in Antarctica and Greenland for studying such records, which can go back to around a million years. Experience shows, however, that the ice-sheet flow generally disrupts the stratigraphy of the bottom part of deep ice cores, destroying the integrity of the oldest records. For all these reasons glaciologists have been studying the microstructure of polar ice cores for decades, in order to understand the genesis and fate of ice-core climate records, as well as to learn more about the physical properties of polar ice, aiming at better climate-record interpretations and ever more precise models of ice-sheet dynamics. In this Part I we review the main difficulties and advances in deep ice core drilling in Antarctica and Greenland, together with the major contributions of deep ice coring to the research on natural ice microstructures. In particular, we discuss in detail the microstructural findings from Camp Century, Byrd, Dye 3, GRIP, GISP2, NorthGRIP, Vostok, Dome C, EDML, and Dome Fuji, besides commenting also on the earlier results of some pioneering ventures, like the Jungfraujoch Expedition and the Norwegian–British–Swedish Antarctic Expedition, among others. In the companion Part II of this work ( Faria et al., 2014), the review proceeds with a survey of the state-of-the-art understanding of natural ice microstructures and some exciting prospects in this field of research.