In:
European Journal of Inorganic Chemistry, Wiley, Vol. 2010, No. 28 ( 2010-10), p. 4526-4531
Abstract:
The catalytic properties of four polyoxometalate (POM)‐based metal‐organic frameworks, {[Cu 2 (4,4′‐bipy) 4 (H 2 O) 4 ](SiW 12 O 40 )(H 2 O) 18 } n ( 1 ), {[Cu 2 (4,4′‐bipy) 4 (H 2 O) 4 ](SiW 12 O 40 )(4,4′‐bipy) 2 (H 2 O) 4 } n ( 2 ), {[Cu 2 (4,4′‐bipy) 4 (H 2 O) 4 ](PW 12 O 40 )(H 2 O) 18 } n ( 3 ), and {[Cu 2 (4,4′‐bipy) 4 (H 2 O) 4 ](PMo 12 O 40 )(H 2 O) 18 } n ( 4 ) (bipy = bipyridine), for the oxidation of ethylbenzene were investigated. Complexes 1 – 4 , which feature 3D frameworks formed through static incorporation between distinct Keggin POMs and the same voids in the 2D network of [Cu 2 (4,4′‐bipy) 4 (H 2 O) 4 ] n 4 n + , show the distinct conversion and selectivity for the oxidation of ethylbenzene. Investigation into the difference in the catalytic activity of 1 – 4 reveals that the oxidation of the substrate was performed in the pore of the framework and that the valence of the metal ion in the polyoxometalates significantly affects the catalytic activity of the 3D framework.
Type of Medium:
Online Resource
ISSN:
1434-1948
,
1099-0682
DOI:
10.1002/ejic.v2010:28
DOI:
10.1002/ejic.201000491
Language:
English
Publisher:
Wiley
Publication Date:
2010
detail.hit.zdb_id:
1475009-0
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