In:
Surface and Interface Analysis, Wiley, Vol. 45, No. 8 ( 2013-08), p. 1206-1210
Abstract:
In this paper, the electronic structures of NbO 2 and Nb 2 O 5 are theoretically and experimentally analyzed. The oxides in the samples are mainly consisted of NbO 2 and NbO, whereas the outmost layer of the samples is NbO 2 . After exposure to air, the outermost layer on all niobium samples is Nb 2 O 5 . The photoelectrons from the first 2–4 Å contribute to the spectra, so the valence band structure of NbO 2 and Nb 2 O 5 can be confirmed from ultraviolet photoelectron spectroscopy (UPS). By comparing the UPS with density of state results, the electronic structure of NbO 2 and Nb 2 O 5 can be distinguished from each other, and then the electronic structure was deconvoluted into several electronic states. The agreement between experimental result and theory is, in the best case, satisfactory. Copyright © 2013 John Wiley & Sons, Ltd.
Type of Medium:
Online Resource
ISSN:
0142-2421
,
1096-9918
Language:
English
Publisher:
Wiley
Publication Date:
2013
detail.hit.zdb_id:
2023881-2
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