GLORIA

GEOMAR Library Ocean Research Information Access

feed icon rss

Your email was sent successfully. Check your inbox.

An error occurred while sending the email. Please try again.

Proceed reservation?

Export
Filter
  • Articles  (4)
  • 2010-2014  (4)
  • 1
    Publication Date: 2022-05-26
    Description: Author Posting. © American Geophysical Union, 2011. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Paleoceanography 26 (2011): PA1212, doi:10.1029/2010PA002022.
    Description: Records of 231Pa/230Th from Atlantic sediments have been interpreted to reflect changes in ocean circulation during the geologic past. Such interpretations should be tested with due regard to the limited spatial coverage of 231Pa/230Th data and the uncertainties in our current understanding of the behavior of both nuclides in the ocean. Here an inverse method is used to evaluate the information contained in 231Pa/230Th compilations for the Holocene, Last Glacial Maximum (LGM), and Heinrich Event 1 (H1). An estimate of the abyssal circulation in the modern Atlantic Ocean is obtained by combining hydrographic observations and dynamical constraints. Then sediment 231Pa/230Th data for each time interval are combined with an advection-scavenging model in order to determine their (in)consistency with the modern circulation estimate. We find that the majority of sediment 231Pa/230Th data for the Holocene, LGM, or H1 can be brought into consistency with the modern circulation if plausible assumptions are made about the large-scale distribution of 231Pa and about model uncertainties. Moreover, the adjustments in the data needed to reach compatibility with a hypothetical state of no flow (no advection) are positively biased for each time interval, suggesting that the 231Pa/230Th data (including that for H1) are more consistent with a persistence of some circulation than with no circulation. Our study does not imply that earlier claims of a circulation change during the LGM or H1 are inaccurate, but that these claims cannot be given a rigorous basis given the current uncertainties involved in the analysis of the 231Pa/230Th data.
    Description: O.M. acknowledges the support from the U.S. National Science Foundation. J.F.M. acknowledges support from the U.S. National Science Foundation and the Comer Research and Education Foundation.
    Keywords: Pa-231/Th-230 ; Meridional overturning circulation ; Inverse method ; Heinrich Event
    Repository Name: Woods Hole Open Access Server
    Type: Article
    Format: application/msword
    Format: application/pdf
    Format: text/plain
    Location Call Number Limitation Availability
    BibTip Others were also interested in ...
  • 2
    Publication Date: 2022-05-26
    Description: Author Posting. © Association for the Sciences of Limnology and Oceanography, 2012. This article is posted here by permission of Association for the Sciences of Limnology and Oceanography for personal use, not for redistribution. The definitive version was published in Limnology and Oceanography: Methods 10 (2012): 464-474, doi:10.4319/lom.2012.10.464.
    Description: The GEOTRACES program requires the analysis of large numbers of seawater samples for 232Th, 230Th, and 231Pa. During the GEOTRACES international intercalibration exercise, we encountered unexpected difficulties with recovery and contamination of these isotopes, 232Th in particular. Experiments were carried out to identify the source of these issues, leading to a more streamlined and efficient procedure. The two particular problems that we identified and corrected were (1) frits in columns supplied by Bio-Rad Laboratories caused loss of Th during column chemistry and (2) new batches of AG1-X8 resin supplied by Bio-Rad Laboratories released more than 100 pg of 232Th during elution of sample. To improve yields and blanks, we implemented a series of changes including switching to Eichrom anion exchange resin (100-200 μm mesh) and Environmental Express columns. All Th and Pa samples were analyzed on a Neptune multi-collector inductively-coupled-plasma mass spectrometer (MC-ICP-MS) using peak hopping of 230Th and 229Th on the central SEM, with either 232Th, 236U (or both) used to monitor for beam intensity. We used in-house laboratory standards to check for machine reproducibility, and the GEOTRACES intercalibration standard to check for accuracy. Over a 1-y period, the 2 s.d. reproducibility on the GEOTRACES SW STD 2010-1 was 2.5% for 230Th, 1.8% for 232Th, and 4% for 231Pa. The lessons learned during this intercalibration process will be of value to those analyzing U-Th-Pa and rare earth elements as part of the GEOTRACES program as well as those using U-series elements in other applications that require high yields and low blanks, such as geochronology.
    Description: Financial support was provided by NSF GEOTRACES Award Number 0926860 and NSF-EAR 81971400.
    Repository Name: Woods Hole Open Access Server
    Type: Article
    Format: application/pdf
    Location Call Number Limitation Availability
    BibTip Others were also interested in ...
  • 3
    Publication Date: 2022-05-26
    Description: Author Posting. © American Geophysical Union, 2009. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Paleoceanography 24 (2009): PA2214, doi:10.1029/2008PA001693.
    Description: The silicic acid leakage hypothesis (SALH) predicts that during glacial periods excess silicic acid was transported from the Southern Ocean to lower latitudes, which favored diatom production over coccolithophorid production and caused a drawdown of atmospheric CO2. Downcore records of 230Th-normalized opal (biogenic silica) fluxes from 31 cores in the Pacific sector of the Southern Ocean were used to compare diatom productivity during the last glacial period to that of the Holocene and to examine the evidence for increased glacial Si export to the tropics. Average glacial opal fluxes south of the modern Antarctic Polar Front (APF) were less than during the Holocene, while average glacial opal fluxes north of the APF were greater than during the Holocene. However, the magnitude of the increase north of the APF was not enough to offset decreased fluxes to the south, resulting in a decrease in opal burial in the Pacific sector of the Southern Ocean during the last glacial period, equivalent to approximately 15 Gt opal ka−1. This is consistent with the work of Chase et al. (2003a), and satisfies the primary requirement of the SALH, assuming that the upwelled supply of Si was approximately equivalent during the Holocene and the glacial period. However, previous results from the equatorial oceans are inconsistent with the other predictions of the SALH, namely that either the Corg:CaCO3 ratio or the rate of opal burial should have increased during glacial periods. We compare the magnitudes of changes in the Southern Ocean and the tropics and suggest that Si escaping the glacial Southern Ocean must have had an alternate destination, possibly the continental margins. There is currently insufficient data to test this hypothesis, but the existence of this sink and its potential impact on glacial pCO2 remain interesting topics for future study.
    Description: Funding for this research was provided in part by the U.S. NSF (grant OPP02-30268). We thank the core repository at LDEO and the Antarctic Research Facility at FSU for providing samples.
    Keywords: Southern Ocean ; Silica cycles ; Paleoceanography
    Repository Name: Woods Hole Open Access Server
    Type: Article
    Format: application/pdf
    Format: image/jpeg
    Format: text/plain
    Location Call Number Limitation Availability
    BibTip Others were also interested in ...
  • 4
    Publication Date: 2022-05-26
    Description: Author Posting. © American Geophysical Union, 2007. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Paleoceanography 22 (2007): PA1216, doi:10.1029/2005PA001235.
    Keywords: Paleoflux ; Th-230
    Repository Name: Woods Hole Open Access Server
    Type: Article
    Format: application/pdf
    Location Call Number Limitation Availability
    BibTip Others were also interested in ...
Close ⊗
This website uses cookies and the analysis tool Matomo. More information can be found here...