Description: Detailed knowledge of the extent of post-genetic modifications affecting shallow submarine hydrocarbons fueled from the deep subsurface is fundamental for evaluating source and reservoir properties. We investigated gases from a submarine high-flux seepage site in the anoxic Eastern Black Sea in order to elucidate molecular and isotopic alterations of low-molecular-weight hydrocarbons (LMWHC) associated with upward migration through the sediment and precipitation of shallow gas hydrates. For this, near-surface sediment pressure cores and free gas venting from the seafloor were collected using autoclave technology at the Batumi seep area at 845 m water depth within the gas hydrate stability zone. Vent gas, gas from pressure core degassing, and from hydrate dissociation were strongly dominated by methane (〉 99.85 mol.% of ∑[C1–C4, CO2]). Molecular ratios of LMWHC (C1/[C2 + C3] 〉 1000) and stable isotopic compositions of methane (δ13C = − 53.5‰ V-PDB; D/H around − 175‰ SMOW) indicated predominant microbial methane formation. C1/C2+ ratios and stable isotopic compositions of LMWHC distinguished three gas types prevailing in the seepage area. Vent gas discharged into bottom waters was depleted in methane by 〉 0.03 mol.% (∑[C1–C4, CO2]) relative to the other gas types and the virtual lack of 14C–CH4 indicated a negligible input of methane from degradation of fresh organic matter. Of all gas types analyzed, vent gas was least affected by molecular fractionation, thus, its origin from the deep subsurface rather than from decomposing hydrates in near-surface sediments is likely. As a result of the anaerobic oxidation of methane, LMWHC in pressure cores in top sediments included smaller methane fractions [0.03 mol.% ∑(C1–C4, CO2)] than gas released from pressure cores of more deeply buried sediments, where the fraction of methane was maximal due to its preferential incorporation in hydrate lattices. No indications for stable carbon isotopic fractionations of methane during hydrate crystallization from vent gas were found. Enrichments of 14C–CH4 (1.4 pMC) in short cores relative to lower abundances (max. 0.6 pMC) in gas from long cores and gas hydrates substantiates recent methanogenesis utilizing modern organic matter deposited in top sediments of this high-flux hydrocarbon seep area.

Description: Based on multibeam bathymetry, high-resolution deep-towed sidescan sonar and Chirp subbottom profiling 32 cold seep sites, already identified in Sahling et al. (2008a), have been studied in an approximately 1000 km2 large area ranging from 800 to 2600 m water depth along the middle slope of the active continental margin offshore Nicaragua. Ground truthing is available from towed camera surveys and coring on seven of the structures. The seeps occur in different settings on the slope: upslope and along the headwall of large submarine slides, as isolated eroded massifs, and forming linear ridges between deeply incised canyons. The seep sites show a wide range regarding their size and morphology, their backscatter intensity patterns, their structure in subbottom profiles, and their fluid venting activity inferred from seafloor observations. Surface extension of the seep sites ranges from less than 200 to more than 1500 m in diameter, and relief height varies between no relief and 180 m. Indications of extruded materials such as mud flows are not observed in the area of the seep sites. Instead the seeps are characterized by high proportions of authigenic carbonates. The carbonates occur as crusts, detritus, or single layers embedded in the seafloor sediments. They appear as high backscatter intensities on sidescan sonar images. On some seep sites living vent fauna indicative of active seepage is observed, but gas bubbles have not been observed. To explain the high morphological variability of the features, we propose a generic model including the interaction of several processes: (1) episodic fluid venting and associated authigenic carbonate formation; (2) background sedimentation and subsidence; (3) linear erosion along canyons and denudation on the slope surface.