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  • AIP Publishing  (6)
  • 2010-2014  (6)
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  • AIP Publishing  (6)
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  • 2010-2014  (6)
Year
  • 1
    Online Resource
    Online Resource
    AIP Publishing ; 2014
    In:  Review of Scientific Instruments Vol. 85, No. 9 ( 2014-09-01)
    In: Review of Scientific Instruments, AIP Publishing, Vol. 85, No. 9 ( 2014-09-01)
    Abstract: Simultaneous determination of the multiple local acoustic and geometrical properties of the thin layer with a high lateral resolution is of great interest in ultrasonic non-destructive evaluation. In this paper, we propose a technique based on the V(z, t) data to simultaneously determine the four local properties of the thin layer, namely, the thickness, the sound velocity, the acoustic impedance, and the density. First, the V(z, t) data are collected from both the thin layer and the reference material. Then the sound velocity and the thickness are calculated by focusing the point-focusing transducer on the front and back surfaces of the thin layer, with the confocal positions determined by averaging the peak positions in the V(z) curves at different frequencies. Second, the acoustic impedance of the thin layer is obtained based on the experimental and theoretical two-dimensional reflection spectrum using the echo from the front surface of the layer. Finally, the density can be obtained by dividing the acoustic impedance by the sound velocity. The four local properties of an aluminum layer are accurately obtained using our method. The largest relative error of determining the four properties is around 1%. This technique opens a new way of simultaneously measuring the multiple local acoustic and geometrical properties of thin layers.
    Type of Medium: Online Resource
    ISSN: 0034-6748 , 1089-7623
    Language: English
    Publisher: AIP Publishing
    Publication Date: 2014
    detail.hit.zdb_id: 209865-9
    detail.hit.zdb_id: 1472905-2
    SSG: 11
    Location Call Number Limitation Availability
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  • 2
    Online Resource
    Online Resource
    AIP Publishing ; 2012
    In:  Review of Scientific Instruments Vol. 83, No. 3 ( 2012-03-01)
    In: Review of Scientific Instruments, AIP Publishing, Vol. 83, No. 3 ( 2012-03-01)
    Abstract: The scanning speed of the two-dimensional stage dominates the efficiency of mechanical scanning measurement systems. This paper focused on a detailed scanning time analysis of conventional raster and spiral scan modes and then proposed two fast alternative scanning modes. Performed on a self-developed scanning acoustic microscope (SAM), the measured images obtained by using the conventional scan mode and fast scan modes are compared. The total scanning time is reduced by 29% of the two proposed fast scan modes. It will offer a better solution for high speed scanning without sacrificing the system stability, and will not introduce additional difficulties to the configuration of scanning measurement systems. They can be easily applied to the mechanical scanning measuring systems with different driving actuators such as piezoelectric, linear motor, dc motor, and so on. The proposed fast raster and square spiral scan modes are realized in SAM, but not specially designed for it. Therefore, they have universal adaptability and can be applied to other scanning measurement systems with two-dimensional mechanical scanning stages, such as atomic force microscope or scanning tunneling microscope.
    Type of Medium: Online Resource
    ISSN: 0034-6748 , 1089-7623
    Language: English
    Publisher: AIP Publishing
    Publication Date: 2012
    detail.hit.zdb_id: 209865-9
    detail.hit.zdb_id: 1472905-2
    SSG: 11
    Location Call Number Limitation Availability
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  • 3
    In: The Journal of Chemical Physics, AIP Publishing, Vol. 140, No. 9 ( 2014-03-07)
    Abstract: The first theoretical exploration of superhalogen properties of polynuclear structures based on pseudohalogen ligand is reported here via a case study on eight triply-bridged [Mg2(CN)5]− clusters. From our high-level ab initio results, all these clusters are superhalogens due to their high vertical electron detachment energies (VDE), of which the largest value is 8.67 eV at coupled-cluster single double triple (CCSD(T)) level. Although outer valence Green's function results are consistent with CCSD(T) in most cases, it overestimates the VDEs of three anions dramatically by more than 1 eV. Therefore, the combined usage of several theoretical methods is important for the accuracy of purely theoretical prediction of superhalogen properties of new structures. Spatial distribution of the extra electron of high-VDE anions here indicates two features: remarkable aggregation on bridging CN units and non-negligible distribution on every CN unit. These two features lower the potential and kinetic energies of the extra electron respectively and thus lead to high VDE. Besides superhalogen properties, the structures, relative stabilities and thermodynamic stabilities with respect to detachment of CN−1 were also investigated for these anions. The collection of these results indicates that polynuclear structures based on pseudohalogen ligand are promising candidates for new superhalogens with enhanced properties.
    Type of Medium: Online Resource
    ISSN: 0021-9606 , 1089-7690
    Language: English
    Publisher: AIP Publishing
    Publication Date: 2014
    detail.hit.zdb_id: 3113-6
    detail.hit.zdb_id: 1473050-9
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  • 4
    Online Resource
    Online Resource
    AIP Publishing ; 2012
    In:  Review of Scientific Instruments Vol. 83, No. 1 ( 2012-01-01)
    In: Review of Scientific Instruments, AIP Publishing, Vol. 83, No. 1 ( 2012-01-01)
    Abstract: For inspection of mechanical properties and integrity of critical components such as integrated circuits or composite materials by acoustic methodology, it is imperative to evaluate their acoustic reflection coefficients, which are in close correlation with the elastic properties, thickness, density, and attenuation and interface adhesion of these layered structures. An experimental method based on angular spectrum to evaluate the acoustic coefficient as a function of the incident angle, θ, and frequency, ω, is presented with high frequency time-resolved acoustic microscopy. In order to achieve a high spatial resolution for evaluation of thin plates with thicknesses about one or two wavelengths, a point focusing transducer with a nominal center frequency of 25 MHz is adopted. By measuring the V(z, t) data in pulse mode, the reflection coefficient, R(θ, ω), can be reconstructed from its two-dimensional spectrum. It brings simplicity to experimental setup and measurement procedure since only single translation of the transducer in the vertical direction is competent for incident angle and frequency acquisition. It overcomes the disadvantages of the conventional methods requiring the spectroscopy for frequency scanning and/or ultrasonic goniometer for angular scanning. Two substrates of aluminum and Plexiglas and four stainless plates with various thicknesses of 100 μm, 150 μm, 200 μm, and 250 μm were applied. The acoustic reflection coefficients are consistent with the corresponding theoretical calculations. It opened the way of non-destructive methodology to evaluate the elastic and geometrical properties of very thin multi-layers structures simultaneously.
    Type of Medium: Online Resource
    ISSN: 0034-6748 , 1089-7623
    Language: English
    Publisher: AIP Publishing
    Publication Date: 2012
    detail.hit.zdb_id: 209865-9
    detail.hit.zdb_id: 1472905-2
    SSG: 11
    Location Call Number Limitation Availability
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  • 5
    In: Journal of Applied Physics, AIP Publishing, Vol. 112, No. 8 ( 2012-10-15)
    Abstract: This paper presents an ultrasonic technique for simultaneous determination of the complete set of acoustical and geometrical properties of a film or a thin layer in a stratified material embedded between two known materials using point-focus ultrasonic spectroscopy, which provides a high lateral resolution. The theoretical model of the two-dimensional spectrum Rt(θ,ω) of the stratified material is calculated as a function of six parameters of the unknown layer: longitudinal and transverse velocities cl, ct, attenuation αl, αt, density ρ, and thickness h, which fully determined the properties of the film. The experimental spectrum Re(θ,ω) can be measured by V(z,t) technique. A two-step algorithm is presented to decompose the searching process of parameters from one six-dimensional to two three-dimensional spaces. The sensitivity of the two-dimensional spectrum to individual properties and its stability against experimental noise are studied. The full set properties of a 250 μm thick stainless steel film and a 930 μm thick SiO2 thin layer of a three layered stratified material immersed in water are determined. The proposed technique used a point-focus transducer, which makes the setup simple and reliable. It allows measurement of the local properties of the film and enables precision material characterization.
    Type of Medium: Online Resource
    ISSN: 0021-8979 , 1089-7550
    Language: English
    Publisher: AIP Publishing
    Publication Date: 2012
    detail.hit.zdb_id: 220641-9
    detail.hit.zdb_id: 3112-4
    detail.hit.zdb_id: 1476463-5
    Location Call Number Limitation Availability
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  • 6
    Online Resource
    Online Resource
    AIP Publishing ; 2012
    In:  Chinese Journal of Chemical Physics Vol. 25, No. 4 ( 2012-08-01), p. 463-468
    In: Chinese Journal of Chemical Physics, AIP Publishing, Vol. 25, No. 4 ( 2012-08-01), p. 463-468
    Abstract: A series of poly(acrylic acid) macromolecular chain transfer agents with different molecular weights were synthesized by reversible addition-fragmentation chain transfer (RAFT) polymerization and characterized by 1H NMR and gel permeation chromatography. Multiresponsive core-shell nanogels were prepared by dispersion polymerization of N-isopropylacrylamide in water using these poly(potassium acrylate) macro-RAFT agents as the electrosteric stabilizer. The size of the nanogels decreases with the amount of the macro-RAFT agent, indicating that the surface area occupied by per polyelectrolyte group is a critical parameter for stabilizing the nanogels. The volume phase transition and the zeta potentials of the nanogels in aqueous solutions were studied by dynamic light scattering and zetasizer analyzer, respectively.
    Type of Medium: Online Resource
    ISSN: 1674-0068 , 2327-2244
    Language: English
    Publisher: AIP Publishing
    Publication Date: 2012
    detail.hit.zdb_id: 2381472-X
    SSG: 6,25
    Location Call Number Limitation Availability
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