ISSN:
1572-8927
Keywords:
Transition metals
;
CoCl2
;
CuCl2
;
MnCl2
;
enthalpy of mixing
;
Pitzer's equations
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Abstract Enthalpies of mixing (Δm H) aqueous solutions of CoCl2, CuCl2, and MnCl2 with NaCl solutions were measured at constant ionic strengths of 0.5, 1.0, and 3.0 molal at 25°C. The excess enthalpy equations of Pitzer were then fit to the resulting Δm H data. The resulting parameters are the temperature derivatives of the activity coefficient mixing parameters in the Pitzer system. The heat of mixing data for CoCl2 and CuCl2 were in agreement with earlier isomolal results by other workers.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF00649243
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