In:
Advanced Energy Materials, Wiley, Vol. 5, No. 22 ( 2015-11)
Abstract:
Sodium‐ion batteries are promising for grid‐scale storage applications due to the natural abundance and low cost of sodium. However, few electrodes that can meet the requirements for practical applications are available today due to the limited routes to exploring new materials. Here, a new strategy is proposed through partially/fully substituting the redox couple of existing negative electrodes in their reduced forms to design the corresponding new positive electrode materials. The power of this strategy is demonstrated through the successful design of new tunnel‐type positive electrode materials of Na 0.61 [Mn 0.61‐ x Fe x Ti 0.39 ]O 2 , composed of non‐toxic and abundant elements: Na, Mn, Fe, Ti. In particular, the designed air‐stable Na 0.61 [Mn 0.27 Fe 0.34 Ti 0.39 ]O 2 shows a usable capacity of ≈90 mAh g −1 , registering the highest value among the tunnel‐type oxides, and a high storage voltage of 3.56 V, corresponding to the Fe 3+ /Fe 4+ redox couple realized for the first time in non‐layered oxides, which was confirmed by X‐ray absorption spectroscopy and Mössbauer spectroscopy. This new strategy would open an exciting route to explore electrode materials for rechargeable batteries.
Type of Medium:
Online Resource
ISSN:
1614-6832
,
1614-6840
DOI:
10.1002/aenm.201501156
Language:
English
Publisher:
Wiley
Publication Date:
2015
detail.hit.zdb_id:
2594556-7
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