In:
Zeitschrift für anorganische und allgemeine Chemie, Wiley, Vol. 642, No. 4 ( 2016-02), p. 323-328
Abstract:
Abstract. Two cadmium(II) coordination polymers, {CdL 2 [(CH 3 ) 2 NH 2 ] 2 · 2DMF} n ( 1 ) and {[Cd 3 L 4 [(CH 3 ) 2 NH 2 ] 2 ] · EtOH · 2DMF} n ( 2 ) were synthesized from the solvothermal reactions of Cd(OAc) 2 · 2H 2 O with 3,3′‐(diazenediyl)dibenzoic acid (H 2 L) in different solvents. Both complexes were characterized by elemental analysis, IR spectroscopy, powder X‐ray diffraction, TG analysis, and single‐crystal X‐ray diffraction. In compound 1 , central cadmium(II) atoms were linked with the surrounding L ligands to generate an infinite 1D chain with repeated rings. Compound 2 displayed a 3D threefold interpenetrating framework based on cage‐like [Cd 3 L 6 ] 8 species and exhibited a 4 12 6 3 topological structure. The results demonstrated that the different solvents had significant effect on the construction of different coordination compounds from the same components. In addition, they exhibited excellent stability and good photocatalytic activity towards the degradation of methylene blue in aqueous solution under UV irradiation.
Type of Medium:
Online Resource
ISSN:
0044-2313
,
1521-3749
DOI:
10.1002/zaac.201500705
Language:
English
Publisher:
Wiley
Publication Date:
2016
detail.hit.zdb_id:
201094-X
detail.hit.zdb_id:
1481139-X
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